34368-66-6

Upstream product

• 34368-65-5 1,2-5,6-di-O-isopropylidene-3-O-(N-phenylcarbamoyl)-α-D-glucofuranose 
• 103-71-9 phenyl isocyanate 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 142072-51-3 ethyl O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-(1->3)-O-(2-O-acetyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 142072-52-4 ethyl O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-(1->3)-O-(2-O-acetyl-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-48-7 C₅₁H₄₉F₃N₂O₁₄S₂ 
• 115533-34-1 ethyl O-<2,4,6-tri-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-47-6 Trifluoro-methanesulfonic acid (4aR,6R,7R,8S,8aR)-2-phenyl-8-phenylcarbamoyloxy-6-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 115533-46-5 Trifluoro-methanesulfonic acid (4aR,6R,7R,8S,8aR)-6-((2R,3R,4S,5R,6S)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-8-phenylcarbamoyloxy-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 142072-45-5 benzyl O-<2,4,6-tri-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-(1->4)-2-acetamido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 115533-44-3 ethyl O-<4,6-O-benzylidene-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-54-5 ethyl O-<4,6-O-benzylidene-2,3-O-(N-phenyliminocarbonyl)-β-D-mannopyranosyl>-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-33-0 methyl 6-O-<2,4,6-tri-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 142072-47-7 benzyl O-<4,6-O-(4-nitrobenzylidene)-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-(1->4)-2-acetamido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 115533-32-9 methyl O-<2,4,6-tri-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 115533-53-4 ethyl O-(4,6-O-benzylidene-2,3-O-carbonyl-β-D-mannopyranosyl)-(1->4)-3,6-dibenzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 142072-50-2 ethyl O-(2-O-acetyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 

Relevant academic research and scientific papers

Synthesis of β-D-mannosides from β-D-glucosides via an intramolecular SN2 reaction at C-2

The selective synthesis of β-D-mannosides was achieved by first synthesizing β-D-glucosides that carry an N-phenylcarbamoyl protecting group at O-3. These derivatives were transformed into the corresponding β-D-mannosides by intramolecular nucleophilic su