115533-44-3

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 115533-40-9 Phenyl-carbamic acid (2S,3R,4S,5R,6R)-2-[(2R,3S,4R,5R,6S)-4-benzyloxy-2-benzyloxymethyl-5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-6-ethylsulfanyl-tetrahydro-pyran-3-yloxy]-3,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-4-yl ester 
• 103-71-9 phenyl isocyanate 
• 115533-29-4 1,2,4,6-tetra-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranose 
• 115533-35-2 ethyl 3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-28-3 Phenyl-carbamic acid (2R,3R,4S,5R,6R)-2,3,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-4-yl ester 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 115533-34-1 ethyl O-<2,4,6-tri-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115559-99-4 2,4,6-tri-O-acetyl-3-O-(N-phenylcarbamoyl)-α-D-glucopyranosyl bromide 
• 34368-65-5 1,2-5,6-di-O-isopropylidene-3-O-(N-phenylcarbamoyl)-α-D-glucofuranose 
• 129519-27-3 2-((6S,7R,8aS)-8-benzyloxy-6-ethylsulfanyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-isoindole-1,3-dione 
• 115533-28-3 3-O-(N-phenylcarbamoyl)-D-glucopyranose 
• 129519-28-4 2-((6S,7R,8aS)-6-ethylsulfanyl-8-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-isoindole-1,3-dione 
• 130539-43-4 ethyl 2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 

Downstream Products

• 115533-48-7 C₅₁H₄₉F₃N₂O₁₄S₂ 
• 142072-53-5 ethyl O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-(1->3)-O-<(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-(1->6)>-O-(2-O-acetyl-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 142072-48-8 ethyl O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 142072-49-9 2-[(2S,3R,4R,5S,6R)-4-Benzyloxy-6-benzyloxymethyl-5-((3aS,4S,5aR,9aR,9bS)-2-ethoxy-2-methyl-8-phenyl-hexahydro-[1,3]dioxolo[4',5':4,5]pyrano[3,2-d][1,3]dioxin-4-yloxy)-2-ethylsulfanyl-tetrahydro-pyran-3-yl]-isoindole-1,3-dione 
• 142072-50-2 ethyl O-(2-O-acetyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-53-4 ethyl O-(4,6-O-benzylidene-2,3-O-carbonyl-β-D-mannopyranosyl)-(1->4)-3,6-dibenzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-54-5 ethyl O-<4,6-O-benzylidene-2,3-O-(N-phenyliminocarbonyl)-β-D-mannopyranosyl>-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 142072-52-4 ethyl O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-(1->3)-O-(2-O-acetyl-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 142072-51-3 ethyl O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-(1->3)-O-(2-O-acetyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-48-7 C₅₁H₄₉F₃N₂O₁₄S₂ 
• 115533-54-5 2-((2S,3R,4R,5S,6R)-4-Benzyloxy-6-benzyloxymethyl-2-ethylsulfanyl-5-{(3aS,4S,5aR,8R,9aR,9bS)-8-phenyl-2-[(Z)-phenylimino]-hexahydro-[1,3]dioxolo[4',5':4,5]pyrano[3,2-d][1,3]dioxin-4-yloxy}-tetrahydro-pyran-3-yl)-isoindole-1,3-dione 
• 115533-53-4 2-[(2S,3R,4R,5S,6R)-4-Benzyloxy-6-benzyloxymethyl-2-ethylsulfanyl-5-((3aS,4S,5aR,8R,9aR,9bS)-2-oxo-8-phenyl-hexahydro-[1,3]dioxolo[4',5':4,5]pyrano[3,2-d][1,3]dioxin-4-yloxy)-tetrahydro-pyran-3-yl]-isoindole-1,3-dione 

Relevant academic research and scientific papers

Synthesis of β-D-mannosides from β-D-glucosides via an intramolecular SN2 reaction at C-2

The selective synthesis of β-D-mannosides was achieved by first synthesizing β-D-glucosides that carry an N-phenylcarbamoyl protecting group at O-3. These derivatives were transformed into the corresponding β-D-mannosides by intramolecular nucleophilic su