3437-90-9Relevant academic research and scientific papers
Copper-Catalyzed Direct and Stereoselective Synthesis of Conjugated Enynes from α-Allenols
Sai, Masahiro,Matsubara, Seijiro
, p. 39 - 43 (2018/11/23)
A novel strategy for the stereoselective synthesis of conjugated enynes directly from α-allenols has been developed. The reaction proceeds with perfect E-selectivity and exhibits high functional group compatibility. This catalytic system can also be applied to the stereoselective synthesis of conjugated dienynes and enediynes. (Figure presented.).
Enantioselective reduction of ketones and imines catalyzed by (CN-Box)ReV-oxo complexes
Nolin, Kristine A.,Ahn, Richard W.,Kobayashi, Yusuke,Kennedy-Smith, Joshua J.,Toste, F. Dean
supporting information; experimental part, p. 9555 - 9562 (2010/10/03)
The development and application of chiral, non-racemic ReV-oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer-Schuster rearrangement/reduction to access enantioenriched allylic alcohols and 2) the enantioselective reduction of imines.
