343853-71-4Relevant academic research and scientific papers
Ambergris and/or indole-like compositions of odoriferous substances
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Page/Page column 17, (2021/02/17)
The present invention primarily relates to the use of one or more compound(s) of formula (I) as fragrance, wherein R is methyl or ethyl and R1 is H, methyl or ethyl. The invention further relates to new fragrance compositions comprising one or
13C Nuclear Magnetic Resonance Spectra of Methoxycyclohexane Derivatives. Rotamer Populations about C-OMe Bonds as indicated by 13C Chemical Shifts of Methoxy- and Ring-carbons and 3JC,H Coupling Constants
Haines, Alan H.,Shandiz, Mohammad Seyedi
, p. 1671 - 1678 (2007/10/02)
Methoxy 13C chemical shifts in methoxycyclohexane derivatives may be rationalized in terms of rotamer populations about the C-OMe bond and δ1-effects caused by steric interaction of the methoxy-group with substituents at the neighbouring 2- and 6-positions.Information on rotamer populations is obtained also from the 13C chemical shifts of C-2 and C-6, and from the three-bond coupling between the proton at C-1 and the methoxy-carbon atom.
