34404-82-5

Basic information

• Product Name: ethyl 2-(2,4,6-trimethylphenyl)cyanoacetate
• Synonyms: ethyl 2-(2,4,6-trimethylphenyl)cyanoacetate
• CAS NO: 34404-82-5
• Molecular Weight: 231.294
• Mol File: 34404-82-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: ethyl 2-(2,4,6-trimethylphenyl)cyanoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-(2,4,6-trimethylphenyl)cyanoacetate(34404-82-5)
• EPA Substance Registry System: ethyl 2-(2,4,6-trimethylphenyl)cyanoacetate(34404-82-5)

Safety Data

• Hazardous Substances Data: 34404-82-5(Hazardous Substances Data)

Upstream product

• 4028-63-1 iodomesitylene 
• 105-56-6 ethyl 2-cyanoacetate 
• 576-83-0 2,4,6-trimethylphenyl bromide 
• 1667-04-5 2-bromomesitylene 

Relevant articles and documents

Arene complexes of transition metals in reactions with nucleophilic reagents: XXX. Reaction of π-halomesitylene [Tetramethyl(ethyl) cyclopentadienyl]rhodium(II) complexes with anions derived from CH acids

Reactions of fluoro-and chloromesitylene π-complexes [(η6-1-Hlg-2,4,6-Me3C6H2) (η5-C5EtMe4)Rh]-(BF4) 2 (Hlg = F, Cl) with diethyl malonate anion in THF or a

Synergistic effect of a bis(proazaphosphatrane) in mild palladium-catalyzed direct α-arylations of nitriles with aryl chlorides

The effect of a bis(proazaphosphatrane) ligand on the palladium-catalyzed direct α-arylation of nitriles with various aryl chlorides under mild conditions is reported. Comparisons of the catalytic properties of this ligand with those of three related mono(proazaphosphatrane)s under the same reaction conditions revealed that bis(proazaphosphatrane) displayed a synergistically enhanced activity. In the presence of the bis(proazaphosphatrane) ligand, ethyl cyanoacetate and primary as well as secondary nitriles were efficiently coupled with a wide variety of aryl chlorides that contained electron-rich, electron-poor, and electron-neutral groups.

Copper(I) Iodide-Promoted Arylation of Ethyl Sodiocyanoacetate

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