344359-71-3

Upstream product

• 124-38-9 carbon dioxide 
• 69485-62-7 3-phenyl-1-propylidenecyclopropane 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 477531-94-5 (2E,4E)-ethyl 7-phenylhepta-2,4-dienoate 
• 104-53-0 3-phenyl-propionaldehyde 
• 67-56-1 methanol 
• 10576-66-6 (2E,4E)-7-phenylhepta-2,4-dienal 
• 37904-38-4 5-phenylpent-1-en-3-ol 
• 79-20-9 acetic acid methyl ester 
• 129413-75-8 (E)-(5-bromopent-3-en-1-yl)benzene 
• 1027473-57-9 Methanesulfonic acid (E)-5-phenyl-pent-2-enyl ester 
• 55282-95-6 ethyl (2E)-5-phenylpent-2-enoate 
• 75553-23-0 (E)-5-phenyl-2-penten-1-ol 
• 122-97-4 3-Phenyl-1-propanol 

Downstream Products

• 344359-68-8 (E)-7-phenylhept-4-enoic acid 
• 1027021-29-9 Methanesulfonic acid (E)-7-phenyl-hept-4-enyl ester 
• 22348-47-6 trans-7-phenyl-hept-4-en-1-ol 

Relevant academic research and scientific papers

Rapid Access to Thiolactone Derivatives through Radical-Mediated Acyl Thiol-Ene and Acyl Thiol-Yne Cyclization

A new synthetic approach to thiolactones that employs an efficient acyl thiol-ene (ATE) or acyl thiol-yne (ATY) cyclization to convert unsaturated thiocarboxylic acid derivatives into thiolactones under very mild conditions is described. The high overall yields, fast kinetics, high diastereoselectivity, excellent regiocontrol, and broad substrate scope of these reaction processes render this a very useful approach for diversity-oriented synthesis and drug discovery efforts. A detailed computational rationale is provided for the observed regiocontrol.

TMSCN/DBU-mediated facile redox transformation of α,β- unsaturated aldehydes to carboxylic acid derivatives

Redox transformation of an α,β-unsaturated aldehyde to a carboxylic acid derivative by means of a combination of TMSCN and DBU was investigated. In addition to the wide use of the carboxylic acid derivatives provided by this reaction, temperature-dependent control of the kinetic or thermodynamic protonation pattern was found to selectively switch the stereochemistry of the acyl group in the product.

Solvent and ligand partition reaction pathways in nickel-mediated carboxylation of methylenecyclopropanes

Methylenecyclopropanes are carboxylated with gaseous carbon dioxide in the presence of a stoichiometric amount of a nickel complex; the reaction pathways are significantly influenced by the reaction solvent and the amine ligand. The Royal Society of Chemi

Iron tricarbonyl stabilized pentadienyl cation as initiator for cascade polycyclizations: A diastereoselective entry into octahydrophenanthrenes

A new example is provided of completely diastereoselective polycyclization, affording the octahydrophenanthrene framework. Generation of an iron tricarbonyl stabilized pentadienyl carbocation is the triggering event of the cascade reaction. The carbocation is generated by anchimerically assisted regiospecific protonation of a double bond adjacent to the iron tricarbonyl diene moiety. Tetrafluoroboric acid ether complex appears to be the optimum reagent, affording good yields, even under catalytic conditions.

Pesticidal activity of functionalized alkenes

The present invention provides non-peptide organic compounds that have a structure analogous to or reminiscent of the TMOF structure and have pesticidal activity. Thus the present invention concerns pesticidal compounds that inhibit digestion in pests by