344411-83-2

Upstream product

• 98394-23-1 [2-Bromo-2-methyl-1-phenyl-prop-(E)-ylidene]-isopropyl-amine 
• 75-31-0 isopropylamine 
• 611-70-1 phenyl isopropyl ketone 
• 10409-54-8 2-bromo-2-methyl-1-phenyl-propan-1-one 
• 137208-24-3 N-isopropyl-2-chloro-2-methyl-1-phenylpropan-1-imine 
• 107-56-2 O,O-diisopropyl hydrogen phosphorodithioate 
• 1068-55-9 isopropylmagnesium chloride 
• 98-88-4 benzoyl chloride 

Downstream Products

• 106700-99-6 2-Chloro-N-isopropyl-N-(2-methyl-1-phenyl-propenyl)-acetamide 

Relevant academic research and scientific papers

Direct access to 2-aryl substituted pyrrolinium salts?for carbon centre based radicals without pyrrolidine-2-ylidene alias cyclic(alkyl)(amino)carbene (CAAC) as a precursor

The synthesis of organic radicals is challenging due to their inherent instability. In recent years, cyclic(alkyl)(amino)carbene (CAAC)-derived 2-substituted pyrrolinium salts have been used as synthons for the synthesis of isolable carbon-based radicals. Herein, we report a direct, easy and convenient method for the synthesis of 2-aryl substituted pyrrolinium salts without using CAAC as a precursor. These cations can be reduced to the corresponding radicals. The influence of the aryl substituent at the C-2 position on radical stabilization and dimerization has been investigated. Because of the large scope of our strategy (capability to modulate different substituents at all the C- and N-centres of the pyrrolinium salts), it has the merit to be an extremely effective and productive route for generating carbon-based radicals whose stability as well as reactivity can be varied.

Reaction of P(IV) Dithio Acids with N-Alkyl-α-chloroketimines

Effect of the substituent on the imine carbon atom on the result of the reaction of P(IV) dithio acids with N-Alkyl-α-chloroketimines has been studied. New types of ketones containing (O,O-diisopropyl phosphorothioyl)sulfanyl and (diphenylphosphinothioyl)

Synthesis and Herbicidal Activity of N-(1-Arylethenyl)-2-chloroacetamides

N-(1-Alkenyl)-2-chloroacetamides, which bear an aryl substituent at the 1-position of the alkenyl moiety, were synthesized and their herbicidal activities were tested.Some of them were active against paddy field weeds.In particular, a new type of chloroac

DEHYDRODIMERIZATION OF IMINES VIA α-BROMOIMINES USING LITHIUM DIISOPROPYLAMIDE

α-Bromoimines were transformed into 1,4-diimines under soft conditions using lithium diisopropylamide in tetrahydrofuran.