344598-93-2

Upstream product

• 73880-51-0 <2-(Dimethylaminomethyl)phenyl>-<(2-hydroxybicyclo<2.2.2>oct-2-yl)methyl>-sulfoxid 
• 18156-74-6 1-(Trimethylsilyl)imidazole 
• 73880-50-9 <2-(Dimethylaminomethyl)phenyl>-methyl-sulfoxid 
• 3724-10-5 2-(methylthio)benzoic acid 
• 73880-49-6 N,N-Dimethyl-<2-(methylthio)benzyl>ammoniumbromid 
• 62778-81-8 2-(Methylthio)benzoesaeure-dimethylamid 

Downstream Products

• 73880-54-3 <(Bicyclo<2.2.2>oct-2-yliden)methyl>-<2-(dimethylaminomethyl)phenyl>-sulfoxid 
• 73880-55-4 <(Bicyclo<2.2.2>-oct-2-en-2-yl)methyl>-<2-(dimethylaminomethyl)phenyl>-sulfoxid 

Relevant academic research and scientific papers

Stereoselective Synthesis of Alcohols, I Synthesis of One-Carbon Homologous Allyl Alcohols from Aldehydes or Ketones

The high yield conversion of aldehydes and ketones 2 to the one-carbon homologous allyl alcohols 3 is achieved by condensation to the vinyl sulfoxides 7, isomerisation to the allyl sulfoxides 9, and subsequent sigmatropic rearrangement.