34560-81-1

Basic information

• Product Name: 1-chloro-2-(propylsulfanyl)benzene
• Synonyms: 1-Chloro-2-(propylsulfanyl)benzene; 2-Chlorophenyl propyl sulfide; benzene, 1-chloro-2-(propylthio)-; Sulfide, o-chlorophenyl propyl
• CAS NO: 34560-81-1
• Molecular Formula: C₉H₁₁ClS
• Molecular Weight: 186.7016
• Mol File: 34560-81-1.mol

Chemical Properties

• Boiling Point: 245.8°C at 760 mmHg
• Flash Point: 102°C
• Density: 1.13g/cm³
• Vapor Pressure: 0.0441mmHg at 25°C
• Refractive Index: 1.563
• CAS DataBase Reference: 1-chloro-2-(propylsulfanyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-2-(propylsulfanyl)benzene(34560-81-1)
• EPA Substance Registry System: 1-chloro-2-(propylsulfanyl)benzene(34560-81-1)

Safety Data

• Hazardous Substances Data: 34560-81-1(Hazardous Substances Data)

Upstream product

• 6320-03-2 2-chlorothiphenol 
• 71-23-8 propan-1-ol 
• 2457-37-6 1-chloro-2-thiocyanatobenzene 

Downstream Products

• 17482-05-2 o-chlorophenyl methyl sulfone 
• 17733-22-1 2-chlorothioanisole 
• 87453-67-6 1,2-bis(propylthio)benzene 
• 184848-14-4 1-Chloro-2-(1-phenylselanyl-propane-1-sulfinyl)-benzene 
• 136445-73-3 1-Chloro-2-(propane-1-sulfinyl)-benzene 

Relevant articles and documents

Diastereoselective radical alkylations of alkyl aryl sulfoxides

1,2-Asymmetric induction in reactions of arylsulfinylated radicals has been examined and compared to the anionic processes. A rule of thumb allowing to predict the stereoselectivity is presented.

Process for the nucleophilic substitution of unactivated aromatic and heteroaromatic substrates

The nucleophilic substitution upon unactivated monocyclic or polycyclic aromatic or heteroaromatic substrates bearing suitable leaving groups can be achieved by catalyzing the substitution of said leaving groups by an anionic nucleophile with a cyclic or acyclic polydentate chelating ligand. Specific products of this reaction can be used in preparing sulfonylurea herbicides.