34602-11-4

Upstream product

• 7035-02-1 o-Methoxybenzyl chloride 
• 138298-13-2 C₁₅H₁₆OS 
• 135-02-4 ortho-anisaldehyde 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 138298-09-6 1-methoxy-2-[(p-tolylsulfinyl)methyl]benzene 
• 19350-70-0 2-methoxybenzaldehyde p-toluenesulfonylhydrazone 

Downstream Products

• 77853-46-4 4-(2-Methoxyphenyl)-butanenitrile 
• 33209-75-5 4-(2-Methoxyphenyl)-butanoic acid 
• 33209-76-6 Ethyl 4-(2-Methoxyphenyl)-butanoate 
• 77853-47-5 3-Methoxycarbonyl-1-(2-methoxyphenyl)-propyl-4-tolylsulfone 
• 77853-41-9 α-(2-Cyanoethyl)-2-methoxybenzyl-4-tolylsulfone 

Relevant academic research and scientific papers

Iron(III) phthalocyanine-chloride-catalyzed synthesis of sulfones from sulfonylhydrazones

In this study, sulfones are synthesized from sulfonylhydrazones catalyzed by iron(III) phthalocyanine chloride. This reaction offers broad substrate scope, occurs under mild conditions, utilized readily available reactants, and forms products in good-to-h

Asymmetric synthesis of aryl benzyl sulfoxides by vanadium-catalysed oxidation: A combination of enantioselective sulfide oxidation and kinetic resolution in sulfoxide oxidation

Enantioselective vanadium-catalysed oxidation of aryl benzyl sulfides using Bolm's procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically >90% ee), albeit with an associated reduction in yield. The effects of ligand, solvent and reaction conditions are discussed in detail. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.

Kinetic resolution in vanadium-catalyzed sulfur oxidation as an efficient route to enantiopure aryl benzyl sulfoxides

Enantiopure aryl benzyl sulfoxides can be prepared using vanadium-Schiff base catalyzed sulfide oxidation and kinetic resolution of the resulting sulfoxide. The kinetic resolution can be effected in combination with asymmetric sulfide oxidation or instead starting from the racemic sulfoxide. Georg Thieme Verlag Stuttgart.