3463-21-6Relevant articles and documents
HOMOLYTIC REACTION OF 1-HYDROSILATRANE WITH PERFLUOROALKYL IODIDES
Voronkov, M. G.,Petukhov, L. P.,Rakhlin, V. I.,Baryshok, V. P.,Shterenberg, B. Z.,et al.
, p. 1991 (1981)
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Reactions of (triethylstannylthioalkyl)trialkoxysilanes and (triethylstannylthioalkyl)trialkoxysilatranes with methyl iodide
Sorokin,Voronkov
experimental part, p. 2056 - 2060 (2009/04/13)
Reactions of (triethylstannylthioalkyl)trimethoxysilanes Et 3SnS(CH2)nSi(OMe)3 (n = 1, 2) and (triethylstannylthioalkyl)trialkoxysilatranes Et3Sn(CH2) n Sa [hereinafter Sa = Si(O
Si-(2-ethoxycarbonylvinyl)-substituted trifluoro-and triethoxysilanes and trans-1-(2-ethoxycarbonylvinyl)silatrane
Baryshok,Kuznetsova,Kopylova,Ivanova,Albanov,Voronkov
, p. 1403 - 1405 (2007/10/03)
Hydrosilylation of (ethoxycarbonyl)acetylene with triethoxysilane was used to obtain triethoxy-(2-ethoxycarbonylvinyl)silane as a mixture of cis and trans isomers. This mixture under the action of the boron trifluoride-ether complex readily converts to a mixture of respective isomers of (2-ethoxycarbonylvinyl)trifluorosilane. trans-Triethoxy(2-ethoxycarbonylvinyl)silane reacts with triethanolamine to give trans-1-(2-ethoxycarbonylvinyl)silatrane in quantitative yield. Transetherification of the isomeric mixture of triethoxy-(2-ethoxycarbonylvinyl)silane with triethanolamine, too, yields trans-1-(2-ethoxycarbonylvinyl)silatrane. Along with this silatrane and ethanol, the latter reaction gives 1-ethoxysilatrane and vinyl acetate.