34755-95-8Relevant academic research and scientific papers
Rhodium-Catalyzed Dehydrogenative Annulation of N-Arylmethanimines with Vinylene Carbonate for Synthesizing Quinolines
Hu, Yan,Nan, Jiang,Yin, Jiacheng,Huang, Guanjie,Ren, Xin,Ma, Yangmin
supporting information, p. 8527 - 8532 (2021/11/13)
Here we report a novel Rh-catalyzed C-H/C-H alkenylation of N-arylmethanimines with vinylene carbonate acting as a vinylene unit. Forty examples of C3,C4-nonsubstituted quinolines were achieved from commercially available starting materials. This identified process features an exceedingly simple system, a lower loading of catalyst, and the capacity for postfunctionalization with bioactive molecules.
Incorporation of steroidal biomarkers into petroleum model compounds
Scherer, Alexander,Hampel, Frank,Gray, Murray R.,Stryker, Jeffrey M.,Tykwinski, Rik R.
experimental part, p. 597 - 606 (2012/08/28)
A series of fully-substituted 5,6-benzoquinolines covalently fused to the chlolestane framework has been synthesized to serve as model compounds for the poorly characterized components found in the heaviest fractions of petroleum, namely the asphaltenes.
A stereoselective Povarov reaction leading to exo-tetrahydroindolo[3,2-c] quinoline derivatives catalyzed by iodine
Wang, Xiang-Shan,Yin, Ming-Yue,Wang, Wei,Tu, Shu-Jiang
experimental part, p. 4811 - 4818 (2012/09/22)
We report an iodine-catalyzed Povarov reaction using indole as dienophile carried out in toluene at room temperature. This three-component reaction, coupling an aldehyde, an amine, and an indole, proved to be an efficient method for synthesizing exo-indol
