34829-90-8Relevant academic research and scientific papers
Synthesis of novel cobalt(III) porphyrin-phosphoryl complexes
Tse, Andy K.-S.,Mak, Kin Wah,Chan, Kin Shing
, p. 2651 - 2655 (1998)
Novel porphyrinato[phosphoryl] cobalt(III) complexes were synthesized unexpectedly through the reaction of BrCoIII(por) (por = porphyrinato dianion) with Me3SiLi (MeLi-Me6Si2-HMPA) and MeLi in HMPA at 78 °C. Phosphoryl complexes were also synthesized from HMPA-K and the appropriate organophosphoryl chloride-K As a result, Me3SiLi may not always be an appropriate silylating agent for bulky organometallic electrophiles.
