3485-55-0Relevant articles and documents
Preparation of N-Tritylamino Acids from N-Trimethylsilylamino Acid Trimethylsilyl Esters
Mamos, Petros,Sanida, Chariklia,Barlos, Kleomenis
, p. 1083 - 1084 (2007/10/02)
Persilylated amino acids are used to prepare Nα-tritylamino acids 2,4, and 6 in high yields by cleavage of the Si-N bond with trityl chloride in chloroform under reflux.The side chains of Lys, Orn and Cys are simultaneously tritylated while sil
PREAPARATION OF TRITYL DERIVATIVES OF AMINO ACIDS WITH THE AID OF THE SILYLATION REACTION
Rabinovich, A. K.,Karelskii, V. N.,Krysin. E. P.,Antonov, A. A.,Smirnov, M. B.,Chipens, G. I.
, p. 205 - 207 (2007/10/02)
A number of N-trityl-substituted amino acids (lysine, glutamine, tyrosine, valine, and proline) have been obtained with the aid of the silylation reaction.Bis(trimethylsilyl)acetamide was used as the silylating agent.The compounds were isolated with good yields and were distinguished by chromatographic homogeneity, and they were characterized by their angles of optical rotation, melting points, and elementary analyses.Their purity was checked by TLC and 13C NMR.