34883-01-7Relevant academic research and scientific papers
Synthesis of substituted resorcinol monomethyl ethers from 2-bromo-3-methoxycyclohex-2-en-1-ones
Shao, Wenjie,Clive, Derrick L. J.
, p. 3211 - 3216 (2015/03/30)
2-Bromo-3-methoxycyclohex-2-en-1-ones are readily alkylated at C-6 with reactive halides, and then treatment with DBU (2 equiv) in PhMe at room temperature results in smooth loss of bromide and aromatization to resorcinol monomethyl ethers of defined substitution pattern.
Synthesis of tetra- and pentasubstituted benzenes from dimedone and derivatives
Nelson,Nelson
, p. 1287 - 1290 (2007/10/02)
Treatment of dimedone (5,5-dimethylcyclohexane-1,3-dione) and derivatives with one molar equivalent of sulfuric acid in trifluoroacetic anhydride leads, via sulfonation and a 1,2-methyl group migration, to a variety of dimethylresorcinol derivatives. The
