4683-45-8

Basic information

• Product Name: 3-methoxy-5,5-dimethylcyclohex-2-en-1-one
• Synonyms: 2-cyclohexen-1-one, 3-methoxy-5,5-dimethyl-; 3-Methoxy-5,5-dimethylcyclohex-2-en-1-one; 5,5-Dimethyl-3-methoxycyclohex-2-enone
• CAS NO: 4683-45-8
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.2063
• Mol File: 4683-45-8.mol
• Article Data: 26

Chemical Properties

• Boiling Point: 239.8°C at 760 mmHg
• Flash Point: 97.2°C
• Density: 0.98g/cm³
• Vapor Pressure: 0.0394mmHg at 25°C
• Refractive Index: 1.466
• CAS DataBase Reference: 3-methoxy-5,5-dimethylcyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methoxy-5,5-dimethylcyclohex-2-en-1-one(4683-45-8)
• EPA Substance Registry System: 3-methoxy-5,5-dimethylcyclohex-2-en-1-one(4683-45-8)

Safety Data

• Hazardous Substances Data: 4683-45-8(Hazardous Substances Data)

Usage

General Description

3-methoxy-5,5-dimethylcyclohex-2-en-1-one is a chemical compound with the molecular formula C10H16O2. It is a cyclic ketone and a derivative of cyclohexenone, containing a methoxy group at the third carbon and two methyl groups at the fifth carbon of the cyclohexene ring. 3-methoxy-5,5-dimethylcyclohex-2-en-1-one is commonly used in the fragrance industry as it provides a sweet, floral, and woody aroma with a touch of spice. It is also utilized in the production of perfumes, soaps, and other scented products. Additionally, it has been studied for its potential medicinal and biological properties, including its antioxidant and anti-inflammatory effects.

Upstream product

• 67-56-1 methanol 
• 53347-71-0 3-Ethanesulfinyl-5,5-dimethyl-cyclohex-2-enone 
• 126-81-8 dimedone 
• 74-88-4 methyl iodide 
• 6267-39-6 3-ethoxy-5,5-dimethyl-2-cyclohexen-1-one 
• 5680-79-5 glycine ethyl ester hydrochloride 
• 31928-99-1 3-allyloxy-5,5-dimethyl-cyclohex-2-enone 
• 877823-43-3 5,5-dimethyl-3-(3-methyl-cyclohexyloxy)-cyclohex-2-enone 
• 877823-42-2 5,5-dimethyl-3-(prop-2-ynyloxy)cyclohex-2-enone 
• 88544-37-0 1-(3-Methoxy-5,5-dimethyl-cyclohex-2-enylidene)-piperidinium; iodide 
• 70-25-7 N-Methyl-N'-nitro-N-nitrosoguanidine 
• 3471-13-4 dimedone 
• 17530-69-7 3-chloro-5,5-dimethylcyclohex-2-en-1-one 
• 124-41-4 sodium methylate 

Downstream Products

• 144648-12-4 5,5-dimethyl-3-<2-(1,3-dioxolan-2-yl)-ethyl>-2-cyclohexen-1-one 
• 132783-38-1 2-Chloro-propionic acid 4-methoxy-6,6-dimethyl-2-oxo-cyclohex-3-enyl ester 
• 121079-98-9 5,5-dimethyl-3-(4-trimethylsilylbut-3-ynyl)cyclohex-2-enone 
• 388570-70-5 TMSOC₆H₄Me₂OMe 
• 118465-27-3 3-(3-butenyl)-5,5-dimethyl-2-cyclohexen-1-ol 
• 76999-39-8 3-(2-oxoethyl)-3--5.5-dimethylcyclohex-1-ene 
• 76999-40-1 [5,5-Dimethyl-1-((E)-2-trimethylsilanyl-vinyl)-cyclohex-2-enyl]-acetic acid 
• 24706-48-7 3-[(4-methoxyphenyl)amino]-5,5-dimethylcyclohex-2-en-1-one 
• 37722-34-2 2-bromo-5,5-dimethyl-3-hydroxycyclohex-2-en-1-one 
• 21428-65-9 2,2-dibromo-5,5-dimethylcyclohexane-1,3-dione 
• 21428-74-0 2,6-dibromo-5,5-dimethyl-3-methoxycyclohex-2-en-1-one 

Relevant articles and documents

Alcoholysis of 3-alkoxy-2-cyclohexene-1-thiones

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Arene Trifunctionalization with Highly Fused Ring Systems through a Domino Aryne Nucleophilic and Diels–Alder Cascade

A convenient and efficient domino aryne process was developed under transition-metal-free conditions to generate a range of tetra- and pentacyclic ring systems. This transformation was realized via a 1,2-benzdiyne through a nucleophilic and Diels–Alder reaction cascade using styrene as the diene moiety. Three new chemical bonds, namely one C?N and two C?C bonds, and two benzofused rings could be constructed concomitantly, which was made possible by distinct chemoselective control at both the 1,2-aryne and 2,3-aryne stages. Moreover, in-depth studies were carried out on the domino aryne precursors and controlling the diastereoselectivity.

Bromine and iodine-cucurbit[6]uril complexes: Preparation and applications in synthetic organic chemistry

Iodine and bromine inclusion compounds were easily prepared by gas diffusion of the halogens using finely powdered CB[6]. A brown powder consisting of I2-CB[6]·4H2O and an orange one of (Br 2)4-CB[6]·10H2O were employed in several different reactions. I2-CB[6] can be used in catalytic reactions giving yields comparable to those reported in the literature. Br 2-CB[6] was effectively applied in electrophilic bromination of benzene and formation of bromohydrin. However, the radical substitution at cyclohexene could not be performed. Overall, based on these results, several applications can be envisioned for these complexes. This journal is the Partner Organisations 2014.