34885-41-1Relevant articles and documents
Thermal and metal-catalyzed rearrangements of bis(stannyl)diazo derivatives into carbodiimides: Carbodiimide-transfer reactions
Veneziani, Guilaine,Réau, Régis,Bertrand, Guy
, p. 4289 - 4290 (2008/10/08)
Thermolysis of bis(trimethylstannyl)diazomethane (1) or bis(tributylstannyl)diazomethane (2) affords the corresponding bis(stannyl)carbodiimides 3-4. Bis(trimethylstannyl)carbodiimide (3) is also obtained at room temperature by palladium-catalyzed isomerization of diazo derivative 1 and is a powerful precursor of elaborated carbodiimides.