34896-80-5

Basic information

• Product Name: 3-BROMOPHENYLMETHYLSULFONE
• Synonyms: 3-BROMOPHENYLMETHYLSULFONE;3-Bromo phenyl methyl;1-Bromo-3-methanesulfonyl-benzene;3-BROMO PHENYL METHYL SULFONE 98%MIN;1-bromo-3-(methylsulfonyl)benzene;3-Bromophenylmethylsulfone ,98%;3-BROMOPHENYLMETHYLS;3-Bromophenyl methyl sulphone
• CAS NO: 34896-80-5
• Molecular Formula: C₇H₇BrO₂S
• Molecular Weight: 235.1
• EINECS: 1312995-182-4
• Product Categories: Miscellaneous;Aromatics Compounds;Aromatics;Sulfur & Selenium Compounds
• Mol File: 34896-80-5.mol
• Article Data: 39

Chemical Properties

• Melting Point: 100-104°C
• Boiling Point: 362.8 °C at 760 mmHg
• Flash Point: 173.2 °C
• Appearance: /
• Density: 1.595g/cm³
• Vapor Pressure: 3.93E-05mmHg at 25°C
• Refractive Index: 1.563
• Storage Temp.: -20°C Freezer
• Solubility: Chloroform
• CAS DataBase Reference: 3-BROMOPHENYLMETHYLSULFONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-BROMOPHENYLMETHYLSULFONE(34896-80-5)
• EPA Substance Registry System: 3-BROMOPHENYLMETHYLSULFONE(34896-80-5)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 34896-80-5(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

InChI:InChI=1/C7H7BrO2S/c1-11(9,10)7-4-2-3-6(8)5-7/h2-5H,1H3

Upstream product

• 77-78-1 dimethyl sulfate 
• 29959-92-0 1-bromo-3-methanesulfinyl-benzene 
• 108-36-1 1,3-dibromobenzene 
• 3996-39-2 [(3-bromophenyl)sulfanyl]acetic acid 
• 3996-51-8 m-bromophenylosulfinylacetic acid 
• 33733-73-2 3-bromo-1-(methylthio)benzene 
• 591-18-4 1-Bromo-3-iodobenzene 
• 20277-69-4 sodium methansulfinate 
• 512-56-1 trimethyl phosphite 
• 6320-01-0 3-Bromothiophenol 
• 89598-96-9 (3-bromophenyl)boronic acid 

Downstream Products

• 178482-89-8 3-(3-Methanesulfonyl-phenyl)-2,3-dihydro-pyrrole-1-carboxylic acid methyl ester 
• 960137-92-2 2-(3-methanesulfonyl-phenyl)-naphthalene-1-carbonitrile 
• 686351-11-1 1-[(1-allylbut-3-enyl)sulfonyl]-3-bromobenzene 
• 851859-80-8 tert-butyl(dimethyl){4-[3-(methylsulfonyl)phenyl]butoxy}silane 
• 1174336-80-1 5-hexyl-3-[3-(methylsulfonyl)phenyl]-1,3-oxazolidin-2-one 
• 160777-44-6 3-(3-Methanesulfonyl-phenyl)-pyridine; hydrochloride 
• 160866-61-5 3-(3-methanesulfonylphenyl)piperidine 
• 504398-38-3 C₁₂H₁₇NO₂S*C₄H₆O₆ 
• 160866-61-5 PNU 180222 
• 156907-84-5 [3H]-(-)-OSU 6162 hydrochloride 
• 93087-51-5 1-(methylsulfonyl)-3-phenoxybenzene 

Relevant articles and documents

Flow Electrosynthesis of Sulfoxides, Sulfones, and Sulfoximines without Supporting Electrolytes

An efficient electrochemical flow process for the selective oxidation of sulfides to sulfoxides and sulfones and of sulfoxides toN-cyanosulfoximines has been developed. In total, 69 examples of sulfoxides, sulfones, andN-cyanosulfoximines have been synthesized in good to excellent yields and with high current efficiencies. The synthesis was assisted and facilitated through a supporting electrolyte-free, fully automated electrochemical protocol that highlights the advantages of flow electrolysis.

A {Ti6W4}-Cluster-Substituted Polyoxotungstate: Synthesis, Structure, and Catalytic Oxidation Properties

A novel Ti-W-O-cluster-substituted tungstoantimonate (TA), [H2N(CH3)2]3Na4H9[{Ti6W4O18(OH)(H2O)3}(B-α-SbW9O33)3]·20H2O (1), has been made by hydrothermal reactions of trivacant [B-α-SbW9O33]9- units, Ti4+ cations, and WO42- anions in the presence of [H2N(CH3)2]·Cl and structurally characterized. Intriguingly, the polyoxoanion of 1 is constructed from three [B-α-SbW9O33]9- units and a previously unobserved decanuclear heterometallic Ti-W-O cluster [Ti6W4O18(OH)(H2O)3]11+ ({Ti6W4}) that is comprised of an octahedral [Ti6WO6(H2O)3]18+ cluster and an edge-sharing [W3O12(OH)]7- fragment via six W-O-Ti/W linkers. Furthermore, studies on the catalytic oxidation properties reveal that 1 possesses good catalytic activity toward the oxidation reactions of various sulfides and cyclooctene based on the environmentally friendly oxidant H2O2.

General sulfone construction: Via sulfur dioxide surrogate control

A highly efficient one-step synthesis of alkyl-alkyl and aryl-alkyl sulfones with a facile combination of halides, sulfur dioxide surrogates and phosphate esters is described. When thiourea dioxide was employed as a reductive sulfur dioxide surrogate, alkyl-alkyl sulfones were obtained under transition metal free conditions. Aryl-alkyl sulfones were obtained with an extremely low catalytic loading (0.2 mol%) via altering the mask of sulfur dioxide surrogates to sodium dithionite. A phosphate ester was employed as a stable and readily available alkyl source. Notably, this protocol has been applied to the late-stage modification of natural products and bioactive molecules.