34907-38-5

Usage

Uses

Used in Pharmaceutical Industry:
2,4,6-TRIS(3,5-DIMETHYLPHENYL)BOROXIN is used as a catalyst for the synthesis of various pharmaceutical compounds. Its ability to facilitate the formation of carbon-carbon bonds is crucial in the production of complex organic molecules that are the basis of many drugs.
Used in Agrochemical Industry:
In the agrochemical sector, 2,4,6-TRIS(3,5-DIMETHYLPHENYL)BOROXIN serves as a catalyst in the synthesis of agrochemicals, contributing to the development of effective pesticides and other agricultural products that require precise molecular structures.
Used in Fine Chemicals Production:
2,4,6-TRIS(3,5-DIMETHYLPHENYL)BOROXIN is utilized as a catalyst in the production of fine chemicals, which are high-purity chemicals used in various applications such as fragrances, dyes, and other specialty chemicals where the formation of specific carbon-carbon bonds is essential.
Used in Chemical Research:
2,4,6-TRIS(3,5-DIMETHYLPHENYL)BOROXIN is also used in academic and industrial research settings as a catalyst to explore new reaction pathways and develop innovative synthetic methods for creating complex organic molecules.
Used in Material Industry:
Due to its high thermal stability, 2,4,6-TRIS(3,5-DIMETHYLPHENYL)BOROXIN finds applications in the material industry, potentially contributing to the development of new materials with specific properties, such as high-temperature resistance or specific catalytic activities.

Upstream product

• 301699-39-8 (4-methoxy-3,5-dimethylphenyl)boronic acid 
• 172975-69-8 3,5-dimethylphenyl boronic acid 
• 182163-96-8 3,4,5-trimethoxyphenylboronic Acid 
• 233584-42-4 4-methoxy-3,5-di-tert-butylphenylboronic acid pinacol ester 
• 98-80-6 phenylboronic acid 
• 121-43-7 Trimethyl borate 
• 34696-73-6 3,5-dimethyphenylmagnesium bromide 

Downstream Products

• 172975-69-8 3,5-dimethylphenyl boronic acid 
• 171195-24-7 tri(3,5-dimethylphenyl)boroxine, morpholine adduct 
• 171195-20-3 tri(3,5-dimethylphenyl)boroxine, 4-picoline adduct 
• 171195-26-9 B₃O₃(CH₃C₆H₃CH₃)3(CH₃C₅H₄N) 
• 171195-21-4 B₃O₃(CH₃C₆H₃CH₃)3(C₉H₇N) 
• 164173-00-6 2-(3,5-dimethylphenyl)naphthalene 
• 1208405-14-4 3-(3,5-dimethylphenyl)-1,2-dihydronaphthalene 
• 1224737-35-2 C₃₃H₄₆O₅ 
• 22445-42-7 3,5-dimethylbenzonitrile 
• 22445-41-6 3,5-dimethylphenyl iodide 
• 171195-22-5 B₃O₃(CH₃C₆H₃CH₃)3(C₆H₁₁NH₂) 
• 171195-27-0 B₃O₃(CH₃C₆H₃CH₃)3(C₆H₅CH₂NH₂) 
• 171195-23-6 B₃O₃(CH₃C₆H₃CH₃)3(C₅H₁₁N) 
• 171195-28-1 B₃O₃(CH₃C₆H₃CH₃)3(CH₃NH₂) 

Relevant academic research and scientific papers

Copper-mediated anomeric: O -arylation with organoboron reagents

Copper-mediated couplings of arylboroxines with glycosyl hemiacetals furnish O-aryl glycosides via Csp2-O bond formation. The method enables the anomeric O-arylation of protected pyranose and furanose derivatives, and is tolerant of functionalized arylboroxine partners. Whereas mixtures of anomers are formed from glucopyranose, galactopyranose and arabinofuranose hemiacetals, the α-anomer is generated selectively from mannopyranose and mannofuranose-derived substrates.

Rhodium-Catalyzed Enantioposition-Selective Hydroarylation of Divinylphosphine Oxides with Aryl Boroxines

The rhodium-catalyzed hydroarylation of divinylphosphine oxides (RP(O)(CH=CH2)2) with aryl boroxines ((ArBO)3) gives the corresponding monoarylation products (RP(O)(CH=CHAr)CH2CH3) in high yields. One of the two vinyl groups in the phosphine oxide undergoes oxidative arylation while the other one is reduced to an ethyl moiety. These reactions proceed with high selectivity in terms of the enantiotopic vinyl groups in the presence of (R)-DTBM-segphos/Rh to give the P-stereogenic monoarylation products with high enantioselectivity.

Copper-Catalyzed Cyanation of Aryl- and Alkenylboronic Reagents with Cyanogen Iodide

Direct catalytic cyanation of organoboronic acids with cyanogen iodide has been achieved by using a copper-bipyridine catalyst system. The cyanation reaction is likely to occur through two catalytic cycles: copper(II)-catalyzed iodination of organoboronic acids and the following cyanidocopper(I)-mediated cyanation of organic iodides.

Nickel-catalyzed efficient and practical Suzuki-Miyaura coupling of alkenyl and aryl carbamates with aryl boroxines

(Figure Presented) Suzuki-Miyaura coupling of unactivated alkenyl carbamates Is described to construct polysubstituted olefins. The developed process is also suitable for heteroaromatic and even electron-rich aromatic carbamates.

Formation of hetero-boroxines: Dynamic combinatorial libraries generated through trimerization of pairs of arylboronic acids

Condensation of pairs of arylboronic acids provided homo- and hetero-boroxines in solution as evidenced from NMR spectra, and those boroxines were detected in the gas phase by GC-MS spectrometry. Equilibrium constants for the formation of these boroxines in solution were obtained through integration of pertinent signals in the NMR spectra of the mixtures ofboronic acids.