233584-42-4

Basic information

• Product Name: (3,5-Di-tert-butyl-4-methoxyphenyl)boronic acid
• Synonyms: (3,5-Di-tert-butyl-4-methoxyphenyl)boronic acid;233584-42-4;(3,5-ditert-butyl-4-methoxyphenyl)boronic acid;Boronic acid, [3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]-;C15H25BO3;3,5-Di-tert-butyl-4-methoxy-phenylboronic acid;(3,5-Di-tert-butyl-4-methoxyphenyl)boronic acidE;(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL) BORONIC ACID
• CAS NO: 233584-42-4
• Molecular Weight: 264.173
• Mol File: 233584-42-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (3,5-Di-tert-butyl-4-methoxyphenyl)boronic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (3,5-Di-tert-butyl-4-methoxyphenyl)boronic acid(233584-42-4)
• EPA Substance Registry System: (3,5-Di-tert-butyl-4-methoxyphenyl)boronic acid(233584-42-4)

Safety Data

• Hazardous Substances Data: 233584-42-4(Hazardous Substances Data)

Usage

General Description

(3,5-Di-tert-butyl-4-methoxyphenyl)boronic acid, also known as DTBMPBA, is a boronic acid derivative with the molecular formula C14H23BO3 and a molecular weight of 248.15 g/mol. It is a white to off-white powder that is sparingly soluble in water and commonly used as a building block in organic synthesis. DTBMPBA is a valuable reagent in Suzuki-Miyaura cross-coupling reactions, which are widely used in the pharmaceutical and agrochemical industries for the synthesis of complex organic compounds. It is also a key intermediate in the production of various pharmaceuticals, pesticides, and materials used in the electronics industry. Additionally, it has been shown to exhibit antioxidant and anti-inflammatory properties, making it a subject of interest in pharmaceutical research.

Upstream product

• 121-43-7 Trimethyl borate 
• 1516-96-7 4-bromo-2,6-di-tert-butylanisole 
• 7732-18-5 water 
• 1139-52-2 4-bromo-2,6-di-tert-butylphenol 
• 1016971-71-3 C₃₃H₄₅B₃O₁₀ 
• 1016971-69-9 C₃₉H₅₇B₃O₈ 
• 1016971-64-4 C₃₁H₄₁B₃O₄ 
• 1016971-63-3 C₃₈H₅₅B₃O₅ 
• 1016971-62-2 C₃₃H₄₅B₃O₆ 
• 1016971-61-1 C₃₉H₅₇B₃O₆ 
• 1016971-60-0 C₄₅H₆₉B₃O₆ 

Downstream Products

• 1016971-62-2 C₃₃H₄₅B₃O₆ 
• 1016971-61-1 C₃₉H₅₇B₃O₆ 
• 1016971-60-0 C₄₅H₆₉B₃O₆ 
• 34907-43-2 tris(4-methoxy-3.5-dimethyl phenyl)boroxine 
• 1016971-64-4 C₃₁H₄₁B₃O₄ 
• 1016971-63-3 C₃₈H₅₅B₃O₅ 
• 34907-38-5 tris(3.5-dimethyl phenyl)boroxine 
• 1016971-56-4 C₂₇H₃₃B₃O₁₂ 
• 1016971-71-3 C₃₃H₄₅B₃O₁₀ 
• 1016971-69-9 C₃₉H₅₇B₃O₈ 
• 1032358-19-2 2-[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 878269-53-5 2,9-bis-(3,5-di-tert-butyl-4-methoxyphenyl)-1,10-phenanthroline 
• 1606141-13-2 1-trifluoromethylthio-4-methoxy-3,5-di-tert-butylbenzene 

Relevant articles and documents

Formation and Activation of Zr/Hf Bis(phenolate-ether) Precatalysts

Zr and Hf complexes of bis(phenolate-ether) (“O4”) ligands feature high activity, stereoselectivity and molecular weight capability for propene polymerization at high temperature. Here we report a simplified ligand synthesis and several new examples of O4

Vaulted biaryls in catalysis: A structure-activity relationship guided tour of the immanent domain of the VANOL ligand

The active site in the BOROX catalyst is a chiral polyborate anion (boroxinate) that is assembled in situ from three equivalents of B(OPh) 3 and one of the VANOL ligand by a molecule of substrate. The substrates are bound to the boroxinate by Hbonds to oxygen atoms O1-O3. The effects of introducing substituents at each position of the naphthalene core of the VANOL ligand are systematically investigated in an aziridination reaction. Substituents in the 4,4′- and 8,8′-positions have a negative effect on catalyst performance, whereas, substituents in the 7- and 7′-positions have the biggest impact in a positive direction. VANOL destination: The active site in the BOROX catalyst is a chiral polyborate anion (boroxinate; see figure) that is assembled in situ from three equivalents of B(OPh)3 and one of the VANOL ligand by a molecule of substrate. The effects of introducing substituents at each position of the naphthalene core of the VANOL ligand are systematically investigated in an aziridination reaction. Copyright

Formation of hetero-boroxines: Dynamic combinatorial libraries generated through trimerization of pairs of arylboronic acids

Condensation of pairs of arylboronic acids provided homo- and hetero-boroxines in solution as evidenced from NMR spectra, and those boroxines were detected in the gas phase by GC-MS spectrometry. Equilibrium constants for the formation of these boroxines in solution were obtained through integration of pertinent signals in the NMR spectra of the mixtures ofboronic acids.