350-45-8Relevant academic research and scientific papers
Deconstructing the Catalytic, Vicinal Difluorination of Alkenes: HF-Free Synthesis and Structural Study of p-TolIF2
Sarie, Jér?me C.,Thiehoff, Christian,Mudd, Richard J.,Daniliuc, Constantin G.,Kehr, Gerald,Gilmour, Ryan
, p. 11792 - 11798 (2017/11/24)
Recently, contemporaneous strategies to achieve the vicinal difluorination of alkenes via an I(I)/I(III) catalysis manifold were independently reported by this laboratory and by Jacobsen and co-workers. Both strategies proceed through a transient ArI(III)
A practical synthetic method of iodoarene difluorides without fluorine gas and mercury salts
Sawaguchi, Masanori,Ayuba, Shinichi,Hara, Shoji
, p. 1802 - 1803 (2007/10/03)
Iodoarene difluorides were synthesized in three steps from the corresponding iodoarenes without the use of dangerous reagents such as fluorine gas of harmful mercury salts.
SYNTHESEN VON ARYLJOD(III)-DIFLUORIDEN DURCH DIREKTFLUORIERUNG VON ARYLJODIDEN
Naumann, D.,Ruether, G.
, p. 213 - 222 (2007/10/02)
The aryl iodides C6H5I, o-XC6H4I(X = F, I), m-FC6H4I and p-XC6H4I (X = F, Cl, Br, I, CH3, NO2) react with elemental fluorine at about -100 deg C in CCl3F to form the corresponding aryl iodine difluorides without attack on the aromatic ring.Preparations, (
