35031-70-0Relevant academic research and scientific papers
Ketide compounds, method for manufacturing, and use for treating diabetes thereof
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Paragraph 0078; 0178-0181; 0199-0201, (2019/08/27)
The present invention relates to ketide compounds, as well as ketide compounds. The present invention relates to a method for preparing a ketide compound, and a use thereof, in which various anti-diabetic TMPA derivative designs can be induced, and is effective in comparison with existing multi-stage synthesis. In addition, the ketide compounds according to the present invention have strong AMPMPK activity and are expected to be useful as a therapeutic agent for diabetes. (by machine translation)
Direct acylation of aryl bromides with aldehydes by palladium catalysis
Ruan, Jiwu,Saidi, Ourida,Iggo, Jonathan A.,Xiao, Jianliang
supporting information; experimental part, p. 10510 - 10511 (2009/02/05)
A new protocol for the direct acylation of aryl bromides with aldehydes is established. It appears to involve palladium-amine cooperative catalysis, affording synthetically important alkyl aryl ketones in moderate to excellent yields in a straightforward manner, and broadening the scope of metal-catalyzed coupling reactions. Copyright
Efficient acylation of toluene and anisole with aliphatic carboxylic acids catalysed by heteropoly salt Cs2.5H0.5PW12O40
Kaur, Jaspal,Kozhevnikov, Ivan V.
, p. 2508 - 2509 (2007/10/03)
Heteropoly salt Cs2.5H0.5PW12O40 is a highly efficient and reusable solid acid catalyst for the liquid-phase acylation of toluene or anisole with C2 - C12 aliphatic carboxylic acids.
Friedel-Crafts Acylation of Arenes Catalysed by Bromopentacarbonylrhenium(I)
Kusama, Hiroyuki,Narasaka, Koichi
, p. 2379 - 2384 (2007/10/03)
The intermolecular Friedel-Crafts acylation of aromatic compounds (such as toluene, m-xylene, and anisole) with various acid chlorides proceeds by using a catalytic amount of bromopentacarbonylrhenium(I) to afford aryl ketones.Intramolecular acylation is also catalyzed by the above-mentioned catalyst to give indanone and tetralone derivatives.
