35058-43-6

Basic information

• Product Name: 6-chlorotetracene-5,12-dione
• CAS NO: 35058-43-6
• Molecular Formula: C₁₈H₉ClO₂
• Molecular Weight: 292.7159
• Mol File: 35058-43-6.mol

Chemical Properties

• Boiling Point: 516.3°C at 760 mmHg
• Flash Point: 215.7°C
• Density: 1.426g/cm³
• Vapor Pressure: 9.09E-11mmHg at 25°C
• Refractive Index: 1.724
• CAS DataBase Reference: 6-chlorotetracene-5,12-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 6-chlorotetracene-5,12-dione(35058-43-6)
• EPA Substance Registry System: 6-chlorotetracene-5,12-dione(35058-43-6)

Safety Data

• Hazardous Substances Data: 35058-43-6(Hazardous Substances Data)

Upstream product

• 85-44-9 phthalic anhydride 
• 855471-67-9 2-(1-chloro-[2]naphthoyl)-benzoic acid 
• 6336-86-3 6-hydroxy-naphthacene-5,12-dione 
• 90-15-3 α-naphthol 
• 10026-13-8 phosphorus pentachloride 
• 59198-77-5 2-((1-hydroxy-2-naphthyl)carbonyl)benzoic acid 
• 98-88-4 benzoyl chloride 
• 858456-17-4 6,12-dichloro-6,12-dihydro-naphthacene-5,11-dione 
• 71038-78-3 5,11-dichlorotetracene 

Downstream Products

• 93834-59-4 6-(N-ethyl-anilino)-naphthacene-5,12-dione 
• 35058-37-8 6-phenylamino-5,12-naphthacenequinone 
• 323577-12-4 4-(6,11-dioxo-6,11-dihydro-naphthacen-5-yloxy)-benzoic acid methyl ester 
• 56408-76-5 6,11-bis(phenylamino)-5,12-naphthacenequinone 
• 444718-45-0 6-amino-11-phenylamino-5,12-naphthacenequinone 
• 287717-73-1 4-(6,11-dioxo-6,11-dihydro-naphthacen-5-yloxy)-benzoic acid 
• 70867-09-3 6-(4-methoxyphenoxy)-5,12-tetracene-5,12-dione 
• 122446-29-1 9-chloro-10-phenylindeno[1,2,3-fg]tetracene 
• 124537-32-2 9,10-diphenylindeno[1,2,3-fg]tetracene 

Relevant articles and documents

Synthesis and Characterization of Electron-Deficient Asymmetrically Substituted Diarylindenotetracenes

Electron-deficient asymmetrically substituted diarylindenotetracenes were prepared via a series of Friedel-Crafts acylations, aryl-aryl cross-couplings, and an intramolecular oxidative cyclization to form the indene ring. Single-crystal X-ray experiments showed good π-π overlap with π-π distances ranging from 3.26 to 3.76 ?. Both thermogravimetric analysis and differential scanning calorimetry indicated that asymmetrically substituted indenotetracenes (ASIs) are stable at elevated temperatures. From cyclic voltammetry experiments, HOMO/LUMO energy levels of ASI derivatives were determined to be near -5.4/-4.0 eV. UV/visible absorption spectra showed strong absorption of light between 400 and 650 nm with molar attenuation coefficients from 104 to 105 M-1 cm-1. ASIs were also found to have very low fluorescence quantum yields, less than 4%. Using the solid-state packing determined from the single-crystal X-ray experiments, computational modeling indicated that ASI molecules should favor electron transport.

PHOTOCHROMIC COMPOUND, TEMPERATURE SENSOR MATERIAL, TEMPERATURE PROBE MATERIAL, OXYGEN CONCENTRATION SENSOR MATERIAL AND OXYGEN CONCENTRATION PROBE MATERIAL

PROBLEM TO BE SOLVED: To provide a photochromic compound that can show light emission in both isomers and has temperature responsiveness and oxygen concentration responsiveness. SOLUTION: A photochromic compound is represented by the following formula (1). (where, A and B are substituents as electron donating groups. Z1 and Z2 are each a substituent selected from hydrogen or an electron acceptor group). SELECTED DRAWING: Figure 4 COPYRIGHT: (C)2018,JPOandINPIT

A photochromic phenoxyquinone based cyanide ion sensor

We have developed a new chemosensor system for cyanide ion that is based on a photochromic material. We observed that addition of cyanide anion to a UV irradiated solution of a phenoxynaphthacenequinone derivative brought about a significant change in the absorption spectra that enabled detection of cyanide ion in a selective and sensitive manner. A carbanion intermediate was shown to be responsible for the long wavelength absorption band (630-940 nm) that is generated by cyanide addition.