351-74-6Relevant academic research and scientific papers
Pushing back the limits of hydrosilylation: Unprecedented catalytic reduction of organic ureas to formamidines
Pouessel, Jacky,Jacquet, Olivier,Cantat, Thibault
, p. 3552 - 3556 (2013)
Pushing back the limits: A novel catalytic transformation has been designed to prepare formamidine derivatives by reduction of substituted ureas with hydrosilanes. Simple iron catalysts based on commercially available iron salts and phosphine ligands prov
Preparation of -, -, and -Bicyclic Guanidines from C,C'-Bis(iminophosphoranes)
Molina, Pedro,Obon, Rosario,Conesa, Carlota,Arques, Antonio,Desamparados Velasco, M. de los,et al.
, p. 1641 - 1652 (2007/10/02)
A one-pot synthesis of -, -, and -rigid bicyclic guanidines (6, 8, 19, 21, 23) based on a bis(iminophosphorane)-mediated annulation strategy is reported.The crystal and molecular structure of the parent -bicyclic guanidine 8 has been established by X-ray diffraction.The crystallographically independent molecule forms dimers through a centre of symmetry by N-H***N hydrogen bonds.The molecule, and therefore the dimer, is statistically disordered in a 65/35 ratio.A statistical study of N-H***N hydrogen bonds of this kind of dimers has been carried out by using the Cambridge Structural Database. - Key Words: Bis(iminophosphoranes) / Guanidines, bicyclic / Aza Wittig reaction
