35171-60-9Relevant articles and documents
A ONE-POT SYNTHESIS OF PENTAFLUORO- AND POLYFLUOROPHENYL ALKYL KETONES
Shen, Yanchang,Qiu, Weiming
, p. 175 - 182 (2007/10/02)
A one-pot synthesis of pentafluoro- and polyfluorophenyl alkyl ketones via ozonolysis of fluorinated phosphoranes is described.In view of the fact that one-pot reaction without isolation of intermediates and the total yield in 3 steps reaches 51-60percent
Reactions with Phosphine Alkylenes, XLII. A Sequence for the Preparation of Acetylenes Starting from Carboxylic Chlorides and Phosphorus Ylides via 1,2-Diketones.
Bestmann, Hans Juergen,Kumar, Kamlesh,Kisielowski, Lothar
, p. 2378 - 2382 (2007/10/02)
Phosphorus ylides 1 and carboxylic chlorides 2 react with transylidation to give acyl ylides 3 which are oxidized with the adduct of ozone to triphenyl phosphite to yield 1,2-diketones 5.These are converted into the bis(hydrazones) 6 which are oxidized with O2/CuCl in pyridine giving acetylenes 7.