3520-52-3

Usage

InChI:InChI=1/C10H14O/c1-3-5-9-7-4-6-8(2)10(9)11/h4,6-7,11H,3,5H2,1-2H3

Upstream product

• 3338-15-6 1-(2-hydroxy-3-methyl-phenyl)-propan-1-one 
• 927822-08-0 2-((E)-prop-1-enyl)-6-methylphenol 
• 1004-66-6 2-methoxy-1,3-dimethylbenzene 
• 26620-08-6 2,6-dimethyl-1-ethoxylbenzene 
• 100-66-3 methoxybenzene 
• 854435-80-6 Opt_.-inakt. 2-Hydroxy-1-methyl-3-propyl-cyclohexan 
• 71-43-2 benzene 
• 3354-58-3 2-allyl-6-methylphenol 
• 95-48-7 ortho-cresol 
• 71-23-8 propan-1-ol 
• 7497-88-3 propionic acid o-toluyl ester 

Downstream Products

• 1011264-22-4 4,N-dihydroxy-3-methyl-5-propyl-benzamidine 
• 207446-97-7 2-methyl-6-propylphenoxyacetic acid 
• 859078-53-8 acetic acid-(2-methyl-6-propyl-phenyl ester) 
• 116496-28-7 2-methyl-6-propyl-[1,4]benzoquinone-4-oxime 

Relevant academic research and scientific papers

Catalytic alkylation of cresols with propanol-1

Study of the reaction of alkylation of ortho-, meta-, and para-cresols with propanol-1 in the presence of ferrite cobalt and manganese catalysts is reported. The effect of the catalyst composition and reaction conditions on the yield and isomeric composit

Ruthenium-catalyzed rearrangement of cis-1-ethynyl-2-vinyloxiranes to substituted phenols

Catalytic cyclization of cis-1-ethynyl-2-vinyloxiranes was implemented with TpRuPPh3(CH3CN)2PF6 catalyst (10 mol%), to give 2,6-disubstituted phenols in reasonable yields. Under similar conditions, 1,1,2,2-tetrasubstituted oxirane gave the 2,3,6-trisubstituted phenol with skeleton reorganization. On the basis of 2H- and l3C-labeling results, we propose that the reaction mechanism involves electrocyclization of ruthenium-vinylidene intermediate with cleavage of the carbon-oxygen bond of the epoxide. Georg Thieme Verlag Stuttgart.

A New Rearrangement of Alkoxybenzyl Anions

Alkyl groups migrate from oxygen to carbon in alkyl aryl ethers which have been metalated in benzylic positions. 2,6-Dimethylanisole provides a variety of 2,6-dialkylphenols and their ethers in 45-80percent yields.Rearrangement products are obtained in 10-30percent yields from other dimethylanisoles and from methylanisoles.The reactions appear to proceed, like Wittig rearrangements, by homolytic cleavage of the alkyl-oxygen bond followed by recombination of the resulting radical pair in a different way.The rearrangements can be avoided by using methyl ethers and working at or below room temperature.