352020-04-3Relevant academic research and scientific papers
A short-step asymmetric synthesis of dehydrodiconiferyl alcohol via C-H insertion reaction
Matsumoto, Shogo,Asakawa, Tomohiro,Hamashima, Yoshitaka,Kan, Toshiyuki
, p. 1082 - 1084 (2012)
A rhodium-catalyzed intramolecular C-H insertion reaction using a chiral auxiliary and a chiral catalyst was employed to achieve double asymmetric induction of a trans-disubstituted dihydrobenzofuran ring, as the key reaction of a stereoselective synthesis of (-)-dehydrodiconiferyl alcohol in 13 steps from commercially available guaiacol. Georg Thieme Verlag Stuttgart · New York.
