1206902-68-2

Basic information

• Product Name: 2-{2-[4-(benzyloxy)-3-methoxybenzyloxy]-5-bromo-3-methoxyphenyl}acetic acid
• Synonyms: 2-{2-[4-(benzyloxy)-3-methoxybenzyloxy]-5-bromo-3-methoxyphenyl}acetic acid
• CAS NO: 1206902-68-2
• Molecular Weight: 487.347
• Mol File: 1206902-68-2.mol

Chemical Properties

• CAS DataBase Reference: 2-{2-[4-(benzyloxy)-3-methoxybenzyloxy]-5-bromo-3-methoxyphenyl}acetic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-{2-[4-(benzyloxy)-3-methoxybenzyloxy]-5-bromo-3-methoxyphenyl}acetic acid(1206902-68-2)
• EPA Substance Registry System: 2-{2-[4-(benzyloxy)-3-methoxybenzyloxy]-5-bromo-3-methoxyphenyl}acetic acid(1206902-68-2)

Safety Data

• Hazardous Substances Data: 1206902-68-2(Hazardous Substances Data)

Upstream product

• 352019-92-2 2-allyl-4-bromo-6-methoxyphenol 
• 90-05-1 2-methoxy-phenol 
• 33693-48-0 4-benzyloxy-3-methoxybenzyl alcohol 
• 72724-00-6 1-(benzyloxy)-4-(bromomethyl)-2-methoxybenzene 
• 7368-78-7 4-bromoguaiacol 
• 2426-87-1 3-methoxy-4-(phenylmethoxy)benzaldehyde 
• 1384190-36-6 2-allyl-4-bromo-6-methoxyphenol 3'-methoxy-4'-benzyloxybenzyl ether 
• 352020-04-3 2-methoxy-4-bromophenol allyl ether 
• 1384190-45-7 C₂₅H₂₇BrO₆ 
• 1384190-46-8 2-{2-[4-(benzyloxy)-3-methoxybenzyloxy]-5-bromo-3-methoxyphenyl}acetaldehyde 

Downstream Products

• 1206902-62-6 methyl 2-{2-[4-(benzyloxy)-3-methoxybenzyloxy]-5-bromo-3-methoxyphenyl}acetate 
• 1384190-48-0 C₃₇H₃₈BrNO₇ 
• 1384190-37-7 C₃₇H₃₆BrN₃O₇ 
• 1384190-38-8 C₃₇H₃₆BrNO₇ 

Relevant articles and documents

A short-step asymmetric synthesis of dehydrodiconiferyl alcohol via C-H insertion reaction

A rhodium-catalyzed intramolecular C-H insertion reaction using a chiral auxiliary and a chiral catalyst was employed to achieve double asymmetric induction of a trans-disubstituted dihydrobenzofuran ring, as the key reaction of a stereoselective synthesis of (-)-dehydrodiconiferyl alcohol in 13 steps from commercially available guaiacol. Georg Thieme Verlag Stuttgart · New York.

Synthesis of dihydrodehydrodiconiferyl alcohol: The revised structure of lawsonicin

Structural revision of lawsonicin, a natural product of Lawsonia alba, is reported based upon comparison of its spectral data with that of the naturally occurring dihydrobenzo[b]furan neolignan (rac)-trans-dihydrodehydrodiconiferyl alcohol, which is found to be identical. A concise synthesis of dihydrodehydrodiconiferyl alcohol, via Rh2[S-DOSP]4-catalysed intramolecular C-H insertion, is described. 10.1039/b918179b The Royal Society of Chemistry 2010.