35331-49-8Relevant articles and documents
Partially Substituted Tetrazenes (Me3E)nN4H4-n (E = Si, Ge, Sn): Preparation, Characterization, and Thermolysis
Wiberg, Nils,Meyers, Rene,Vasisht, Sham Kumar,Bayer, Heiner
, p. 2886 - 2899 (2007/10/02)
Partially substituted tetrazenes (Me3E)nN4H4-n (E = Si, Ge, Sn) can be prepared by protolysis of higher substituted tetrazenes (Me3E)oN4H4-o (o > n) or by silylation, germylation, or stannylation of lower substituted tetrazenes (Me3E)mN4H4-m (m 140 deg C1/2 = 3/4 h), of (Me3Si)2N-N=N-NH2 to Me3SiN3 and Me3SiNH2 (concentrated solution; τ40 deg C1/2 ca. 1/4 h), and of (Me3Si)HN-N=N-NH(SiMe3) to N2 and (Me3Si)2N-NH2 (dilute solution; τ140 deg C1/2 > 1 h) or to HN3 and (Me3Si)2NH (concentrated solution; τ140 deg C1/2 1 h).