13272-02-1

Basic information

• Product Name: Hydrazine, tris(trimethylsilyl)-
• CAS NO: 13272-02-1
• Molecular Formula: C9H28N2Si3
• Molecular Weight: 248.591
• Mol File: 13272-02-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Hydrazine, tris(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydrazine, tris(trimethylsilyl)-(13272-02-1)
• EPA Substance Registry System: Hydrazine, tris(trimethylsilyl)-(13272-02-1)

Safety Data

• Hazardous Substances Data: 13272-02-1(Hazardous Substances Data)

Upstream product

• 58971-25-8 4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide 
• 5936-98-1 trichloromethyltrimethylsilane 
• 15114-92-8 Dilithium N,N'-bis(trimethylsilyl)hydrazide tetramer 
• 176727-41-6 pentkis(trimethylsilyl)-3-phospha-2-pentazene 
• 35331-49-8 Tris(trimethylsilyl)tetrazen 
• 15114-92-8 monolithium 1,2-bis(trimethylsilyl)hydrazine 
• 7758-95-4 lead(II) chloride 
• 176727-48-3 dichloro[tris(trimethylsilyl)hydrazino]arsane 
• 67-56-1 methanol 
• 128336-87-8 trans-1,1,4,4-tetrakis(trimethylsilyl)-2-arsa-2-tetrazene 

Relevant articles and documents

SILYL-NITROGEN COMPOUNDS I. REACTIONS OF DILITHIUM BIS(TRIMETHYLSILYLL)HYDRAZINE WITH GROUP IV HALIDES

Dilithium 1,2-bis(trimethylsilyl)hydrazine (1) reacts with CCl4, Me3SiCCl3 and CBr4 to form predominantly bis(trimethylsilyl)aminocarbonimidic dichloride, bis(trimethylsilyl)aminoisocyanide and bis(trimethylsilyl)diazene, whereas similar reactions with HCCl3, HCI3, H2CCl2, H2CI2, C2H4Cl2 or C2H2Cl4 lead to increasing amounts of bis(trimethylsilyl)hydrazine.In addition to the hydrazone, (Me3Si)2N-N=CH(Cl), the reaction of 1 with CHCl3 forms a small amount of triazasilacyclopentane,.............. .In contrast, Me2SnCl2 reacts with 1 to give tetraazadistannacyclohexane (Me2Sn(NSiMe3)2)2, whereas SnCl4, SnCl2 and PbCl2 act mainly as oxidants and Me2SiCl2 forms polymers.Another product of the reaction of 1 with SnCl2 or PbCl2 is LiN(SiMe3)2 originating perhaps from LiNH(SiMe3) or (LiNN(SiMe3)2)2.

SILYL-NITROGEN COMPOUNDS, II: SYNTHESIS AND CHARACTERISATION OF TETRASILA-PHOSPHA AND TETRASILA-ARSA TETRAZENES

Lithylated bis(trimethylsilyl)hydrazines, Li2N2(SiMe3)2 and LiHN2(SiMe3)2 react with (Me3Si)2NECl2 (E = P or As) to form hetero atom incorporated tetrazenes, 1,3,4,4-tetrakis(trimethylsilyl)-2-phospha-1-tetrazene (Me3Si)2N-N(SiMe3)-P=NSiMe3 and 1,1,4,4-tetrakis(trimethylsilyl)-2-arsa-2-tetrazene (Me3Si)2N-N=As-N(siMe3)2.The former thermolyses primarily into trisila-phosphatriazene (Me3Si)2N-P=NSiMe3 and tetrasilahydrazine (Me3Si)4N2, whereas, the latter forms tris(trimethylsilyl)hydrazine (Me3Si)3N2H.Phosphatetrazene interacts with CH3OH in an oxidative addition reaction to form -(trimethylsilylimino)-(methoxy)-phosphorane, Me3Si)2N-N(SiMe3)-PH(OCH3)(=NSiMe3), whereas, arsatetrazene undergoes cleavage reaction to yield (Me3Si)3N2H.

Transfer of Hydrogen from (Trimethylsilyl)diazene

-