35426-69-8

Basic information

• Product Name: Carbamic acid, (2-chlorophenyl)-, 1,1-dimethylethyl ester
• CAS NO: 35426-69-8
• Molecular Formula: C11H14ClNO2
• Molecular Weight: 227.691
• Mol File: 35426-69-8.mol

Chemical Properties

• CAS DataBase Reference: Carbamic acid, (2-chlorophenyl)-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (2-chlorophenyl)-, 1,1-dimethylethyl ester(35426-69-8)
• EPA Substance Registry System: Carbamic acid, (2-chlorophenyl)-, 1,1-dimethylethyl ester(35426-69-8)

Safety Data

• Hazardous Substances Data: 35426-69-8(Hazardous Substances Data)

Upstream product

• 3320-83-0 o-chlorophenyl isocyanate 
• 75-65-0 tert-butyl alcohol 
• 36016-38-3 tert-Butyl N-hydroxycarbamate 
• 3422-01-3 tert-butyl phenylcarbamate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 62-53-3 aniline 
• 1538-75-6 2,2-dimethylpropanoic anhydride 
• 95-51-2 o-chloroaniline 
• 114-38-5 (2-chlorophenyl)urea 
• 1907-33-1 lithium tert-butoxide 
• 507-40-4 tert-butylhypochlorite 
• 103-71-9 phenyl isocyanate 

Downstream Products

• 138344-50-0 tert-butyl [1,1′-biphenyl]-2-ylcarbamate 
• 90-41-5 2-phenylaniline 
• 1425794-19-9 2-(2,4-dimethylphenylsulfanyl)phenyl carbamic acid tert-butyl ester 
• 95-51-2 o-chloroaniline 

Relevant articles and documents

PRODUCTION METHOD FOR AMIDATE COMPOUND

A method for producing an amidate compound represented by Formula (3), comprising reacting a urethane compound represented by Formula (1) with a carboxylate compound represented by Formula (2): (in the formulas, A, n, R1, R2, R3, R4, R5, R6, X, and a are as described in the Description).

Amidate compound, catalyst for polyurethane production, and method for producing polyurethane resin

Provided is an amidate compound represented by the formula (1): wherein A is a substituted or unsubstituted hydrocarbon group, n is an integer of 1 or more, and D is a nitrogen-containing organic group represented by the formula (2): wherein R1, R2, and R3 are the same or different, and are each a hydrocarbon group that may contain a heteroatom; some or all of R1, R2, and R3 may be bonded together to form a ring structure; X is a nitrogen atom, an oxygen atom, or a sulfur atom; and a is 0 or 1, wherein a is 1 when X is a nitrogen atom, and a is 0 when X is an oxygen atom or a sulfur atom.

Palladium-Catalyzed Decarboxylative Synthesis of Arylamines

A novel approach has been developed for the synthesis of arylamines via the palladium-catalyzed intramolecular decarboxylative coupling (IDC) of aroyloxycarbamates, obtained in situ by reacting aryl carboxylic acids with hydroxycarbamates. The reaction offers facile access to structurally diverse arylamines with the site-specific formation of the C(sp2)-N bond under mild conditions.

Highly ortho-Selective Chlorination of Anilines Using a Secondary Ammonium Salt Organocatalyst

An organocatalytic, highly facile, efficient, and regioselective ortho-chlorination of anilines is described. A secondary ammonium chloride salt has been employed as the catalyst and the reaction can be conducted at room temperature without protection from air and moisture. In addition, the reaction is readily scalable and the catalyst can be recycled and reused. This catalytic protocol has been applied to the efficient synthesis of a highly potent c-Met kinase inhibitor. Mechanistic studies revealed that unique structural features of the secondary ammonium chloride salt are important for both the catalysis and regioselectivity of the electrophilic ortho-chlorination.

Zinc chloride promoted efficient and facile BOC protection of amines

Amines are efficiently protected as their BOC derivatives under mild reaction conditions when reacted with BOC anhydride in presence of ZnCl2. The present method is applicable to a variety of amines including aliphatic, aromatic as well as heteroaromatic amines. This protocol appears to be competitive and in some cases superior to previously reported procedures that work under basic conditions.

A convenient transformation of N-substituted ureas into N-(t-butoxycarbonyl)amines using a copper(II) salt-lithium t-butoxide system

Treatment of N-substituted ureas with a copper(II) reagent prepared from lithium t-butoxide and copper(II) halide led to give the corresponding N-(t-butoxycarbonyl)amines under mild conditions. On the contrary, no reaction of N,N-disubstituted ureas proce

Fungicides for the control of take-all disease of plants

A method of controlling Take-All disease of plants by applying a fungicide of the formula STR1 wherein Z1 and Z2 are C and are part of an aromatic ring which is benzothiophene; and A is selected from --C(X)-amine wherein the amine is an unsubstituted, monosubstituted or disubstituted amino radical, --C(O)--SR3, --NH--C(X)R4, and --C(=NR3)--XR7 ; B is --Wm --Q(R2)3 or selected from O-tolyl, 1-naphthyl, 2-naphthyl, and 9-phenanthryl, each optionally substituted with halogen or R4 ; Q is C, Si, Ge, or Sn; W is --C(R3)p H(2-p) --; or when Q is C, W is selected from --C(R3)p H(2-p), --N(R3)m H(1-m)--, --S(O)p--, and --O--; X is 0 or S; n is 0, 1, 2, or 3; m is 0 or 1; p is 0, 1, or 2; each R and R2 is independently defined herein; R3 is C1 -C4 alkyl; R4 is C1 -C4 alkyl, haloalkyl, alkoxy, alkylthio, alkylamino, or dialkylamino; and R7 is C1 -C4 alkyl, haloalkyl, or phenyl, optionally substituted with halo, nitro, or R4 ; or an agronomic salt thereof.