35453-05-5

Basic information

• Product Name: methyl[(E)-1-(methylsulfinyl)-2-phenylvinyl]sulfane
• Synonyms: methyl[(E)-1-(methylsulfinyl)-2-phenylvinyl]sulfane
• CAS NO: 35453-05-5
• Molecular Weight: 212.337
• Mol File: 35453-05-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl[(E)-1-(methylsulfinyl)-2-phenylvinyl]sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: methyl[(E)-1-(methylsulfinyl)-2-phenylvinyl]sulfane(35453-05-5)
• EPA Substance Registry System: methyl[(E)-1-(methylsulfinyl)-2-phenylvinyl]sulfane(35453-05-5)

Safety Data

• Hazardous Substances Data: 35453-05-5(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 33577-16-1 methyl methylsulfinylmethyl sulfide 
• 52977-22-7 Acetic acid 2-methanesulfinyl-2-methylsulfanyl-1-phenyl-ethyl ester 
• 2168-85-6 methyl phenyldithioacetate 
• 74-88-4 methyl iodide 

Downstream Products

• 15436-06-3 (E)-β-(methylthio)styrene 
• 14063-69-5 β,β-bis(methylthio)styrene 
• 1128143-83-8 2-(methylsulfanyl)-3-phenylbenzofuran 
• 39478-05-2 2-butyl-3-phenylbenzofuran 
• 95703-25-6 2-benzyl-3-phenylbenzofuran 
• 33104-08-4 2-methyl-3-phenylbenzofuran 
• 132354-05-3 methyl 2-chloro-2-phenylthioacetate 
• 22946-46-9 methyl α-phenyl-α-methylthio-thioacetate 
• 69914-26-7 β,β-Bis-(methylsulfinyl)-styrol 
• 69914-27-8 1,1-bis(methylsulfonyl)-2-phenylethene 
• 5925-74-6 S-methyl 2-phenylethanethioate 
• 1669-98-3 Ethyl methyl sulfoxide 
• 7715-02-8 (2-methylsulfanylvinyl)benzene 
• 74-93-1 methylthiol 

Relevant articles and documents

Highly chemoselective oxidation of dithioester enethiolates to sulfenates: Application to the synthesis of ketene dithioacetal S-oxides

Enethiolates derived from dithioesters were efficiently converted into the corresponding vinyl sulfenates by oxidation with a unique N-sulfonyloxaziridine 1a derived from pinacolone. Subsequent alkylation with alkyl halides led to ketene dithioacetal S-oxides in good to excellent yields.

Practical and scalable syntheses of substituted ketene dithioacetal monoxides

Practical syntheses of substituted ketene dithioacetal monoxides (KDMs) from the corresponding aldehydes or ethyl trifluoroacetate are described. Newly developed procedures are scalable and versatile to provide aryl-, alkyl-, and trifluoromethyl-substitut