35467-39-1

Basic information

• Product Name: Benzene, 1,1'-(3-methyl-1-butenylidene)bis-
• CAS NO: 35467-39-1
• Molecular Formula: C17H18
• Molecular Weight: 222.33
• Mol File: 35467-39-1.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(3-methyl-1-butenylidene)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(3-methyl-1-butenylidene)bis-(35467-39-1)
• EPA Substance Registry System: Benzene, 1,1'-(3-methyl-1-butenylidene)bis-(35467-39-1)

Safety Data

• Hazardous Substances Data: 35467-39-1(Hazardous Substances Data)

Upstream product

• 33795-03-8 2,2-dimethyl-1,4,4-triphenylbut-3-en-1-one 
• 13112-46-4 2,2-diphenyl-1-phenylthioethene 
• 30615-19-1 isopropylmercury(II) chloride 
• 19997-66-1 1-iodo-2,2-diphenylethylene 
• 26189-62-8 phenyl 2,2-diphenylethenyl sulfone 
• 556-24-1 methyl 3-methylbutanoate 
• 590-86-3 isovaleraldehyde 
• 71-43-2 benzene 
• 2397-67-3 triisopropylaluminium 
• 67341-86-0 Ph₂CCHHgBr 
• 100954-03-8 phenyl 3-phenylprop-2-ynoate 
• 78-84-2 isobutyraldehyde 
• 582-62-7 3-methyl-1-phenylbutan-1-one 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 99943-04-1 2-acetoxy-3-methyl-1,1-diphenylbutan-1-ol 
• 22133-84-2 2-bromo-1,1-diphenyl-3-methylbutene 
• 1380439-66-6 (3-methylbut-1-ene-1,1,2-triyl)tribenzene 
• 32134-41-1 1,1'-(2,2-dimethylcyclopropylidene)bis(benzene) 
• 33830-03-4 2.2-Dibromo-1.1-diphenyl-3-isopropylcyclopropan 
• 88074-05-9 C₁₈H₁₈Cl₂ 

Relevant articles and documents

Visible-light-mediated alkylation of 4-alkyl-1,4-dihydropyridines with alkenyl sulfones

Herein we report a mild, general protocol for visible-light-mediated alkylation of 4-alkyl-1,4-dihydropyridines with alkenyl sulfones. The protocol permits efficient functionalization of sulfones with a broad range of cyclic and acyclic secondary and tert

RETRACTED ARTICLE: Copper-Catalyzed Decarboxylative C(sp2)-C(sp3) and C(sp)-C(sp3) Coupling of Substituted Cinnamic Acids and 3-Phenyl Propiolic Acid with N-Tosyl Oxaziridines

A mild and efficient strategy for decarboxylative C(sp2)-C(sp3) and C(sp)-C(sp3) coupling of α,β-unsaturated carboxylic acids such as substituted cinnamic acids and 3-phenyl propiolic acid with N-Tosyl oxaziridines was developed. The corresponding products were achieved in moderate to good yields with excellent stereoselectivity. Base-free and oxidant-free conditions allow good functional group tolerance. Radical inhibitors such as TEMPO and BHT completely suppressed the reactions suggesting a radical mechanism was involved. This study is supposed to broaden the frontier of oxaziridines' chemistry and to open up a novel cascade for alkylating reagents.

Mn(II)-catalyzed C-H alkylation of imidazopyridines and N-heteroarenes via decarbonylative and cross-dehydrogenative coupling

A Mn(II)-catalyzed efficient C-H alkylation of imidazoheterocycles and N-heteroarenes with aliphatic aldehydes has been developed via oxidative decarbonylation. Other alkylating agents such as cyclic alkanes, ethers, and alcohols also coupled with N-heteroarenes through cross-dehydrogenative coupling. Regioselectively C5-alkylated imidazoheterocycles were synthesized in good yields. Experimental results show that radical pathway might be involved in this reaction.