35517-66-9Relevant academic research and scientific papers
N-heterocyclic carbene copper(i) catalysed N-methylation of amines using CO2
Santoro, Orlando,Lazreg, Fama,Minenkov, Yury,Cavallo, Luigi,Cazin, Catherine S. J.
, p. 18138 - 18144 (2015/10/28)
The N-methylation of amines using CO2 and PhSiH3 as source of CH3 was efficiently performed using a N-heterocyclic carbene copper(i) complex. The methodology was found compatible with aromatic and aliphatic primary and secondary amines. Synthetic and computational studies have been carried out to support the proposed reaction mechanism for this transformation.
Synthesis of α-Aminocyclobutanones by the Photolytic Reaction of Chromium-Aminocarbene Complexes with Olefins
Soederberg, Bjoern C.,Hegedus, Louis S.
, p. 2209 - 2212 (2007/10/02)
Photolysis of chromium-(N-phenylamino)carbene complexes in the presence of cyclohexadiene, cyclopentadiene, and dihydropyran produced bicyclic cyclobutanones in modest yields.
