35531-59-0Relevant academic research and scientific papers
Mechanism of the Water-Catalyzed Photoisomerization of p-Nitrobenzaldehyde
Wubbels, Gene G.,Kalhorn, Thomas F.,Johnson, Douglas E.,Campbell, Dana
, p. 4664 - 4670 (1982)
p-Nitrobenzaldehyde is observed to photoisomerize cleanly to p-nitrobenzoic acid in aqueous solutions but to be photostable in pure acetonitrile or acetic acid.The dimethyl acetal of p-nitrobenzaldehyde is photostable in water.The quantum yield (0.034 at
Nitration and Oxidation of Substituted Benzaldehydes in Solutions of Dinitrogen Pentaoxide or Nitronium Trifluoromethanesulfonate in Nitric Acid
Moodie, Roy B.,Willmer, Richard
, p. 229 - 234 (2007/10/02)
The competition between oxidation to the corresponding benzoic acid and nitration in the aromatic ring of some substituted benzaldehydes has been probed by kinetic and product studies.Nitrodeformylation was not detected. 4-Carboxybenzaldehyde is nitrated
1,3-Dithienium- and 1,3-Dithiolenium Salts, IV. 1,3-Dithian-2-ylium Tetrafluoroborates - New Agents for the Synthesis of 1-Deuterioaldehydes
Stahl, Ingfried
, p. 3166 - 3171 (2007/10/02)
The 1,3-dithian-2-ylium tetrafluoroborates 3 react in good yields with sodium borohydride (4) to give the 1,3-dithianes 6 and with sodium borodeuteride (5) to form the precursors 7 of 1-deuterated aldehydes 8.Three 1-deuterioaldehydes 8 are synthesized exemplarily by dethioacetalization of 7.
