Mechanism of the Water-Catalyzed Photoisomerization of p-Nitrobenzaldehyde

DOI: 10.1021/jo00145a012

Source and publish data:

Journal of Organic Chemistry p. 4664 - 4670 (1982)

Update date:2022-08-05

Topics: Catalyst Mechanism Photoisomerization Absorption

Authors:

Wubbels, Gene G.

Kalhorn, Thomas F.

Johnson, Douglas E.

Campbell, Dana

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Article abstract of DOI:10.1021/jo00145a012

p-Nitrobenzaldehyde is observed to photoisomerize cleanly to p-nitrobenzoic acid in aqueous solutions but to be photostable in pure acetonitrile or acetic acid.The dimethyl acetal of p-nitrobenzaldehyde is photostable in water.The quantum yield (0.034 at

Full text of DOI:10.1021/jo00145a012

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