35580-98-4

Basic information

• Product Name: Carbamic acid, diethyl-, 2-hydroxyphenyl ester
• CAS NO: 35580-98-4
• Molecular Formula: C11H15NO3
• Molecular Weight: 209.245
• Mol File: 35580-98-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Carbamic acid, diethyl-, 2-hydroxyphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, diethyl-, 2-hydroxyphenyl ester(35580-98-4)
• EPA Substance Registry System: Carbamic acid, diethyl-, 2-hydroxyphenyl ester(35580-98-4)

Safety Data

• Hazardous Substances Data: 35580-98-4(Hazardous Substances Data)

Upstream product

• 65009-00-9 O-phenyl N,N-diethylcarbamate 
• 1228447-82-2 2-(iso-propoxydimethylsilyl)phenyl diethylcarbamate 
• 1696-17-9 N,N-diethylbenzamide 
• 88-10-8 N,N-diethylcarbamyl chloride 
• 108-95-2 phenol 
• 109-89-7 diethylamine 
• 2171-74-6 1,3-benzodioxol-2-one 

Relevant articles and documents

Aerobic C(sp2)-H Hydroxylations of 2-Aryloxazolines: Fast Access to Excited-State Intramolecular Proton Transfer (ESIPT)-Based Luminophores

The direct hydroxylation of 2-aryloxazolines via a deprotonative magnesiation using TMPMgCl·LiCl and subsequent oxidation with molecular oxygen or air as a green oxidant is reported. This method proceeds under mild conditions at room temperature with high regioselectivity and chemoselectivity. The obtained phenols exhibit tunable luminescence properties, induced by excited-state intramolecular proton transfer. This method opens a new opportunity for the sustainable synthesis of luminescent organic molecules.

Ortho-and para-selective ruthenium-catalyzed C(sp2)-H oxygenations of phenol derivatives

Versatile ruthenium catalysts allowed for efficient direct oxygenations of aryl carbamates under remarkably mild reaction conditions. In addition to chelation-assisted C-H activation, the optimized ruthenium catalyst proved amenable to para-selective hydroxylations of anisoles without Lewis basic directing groups.

Hydroxylation of carbanions with lithium teri-butyl peroxide acting as an oxenoid

The lithium salt of terf-butyl hydroperoxide can convert alkyl, vinyl, aryl carbanions, acetylides and various enolates into the corresponding hydroxylated derivatives in good yields and under mild conditions. Eisevier.