356070-10-5Relevant articles and documents
Silylated cyclohexadienes in radical chain hydrosilylations
Amrein, Stephan,Studer, Armido
, p. 3559 - 3574 (2002)
A new method for the mild radical hydrosilylation of alkenes and alkynes is described. Silylated cyclohexadienes that can be readily prepared on large scale are used as radical hydrosilylating reagents. Nonactivated alkenes and alkynes are hydrosilylated in high yields. The reaction can be combined with C-C bond formation, as demonstrated for the preparation of silylated cycloalkanes from the corresponding dienes. Furthermore, radical hydrosilylations in combination with β-fragmentation reactions for the synthesis of allylsilanes and hydrosilylations of aldehydes and ketones providing protected alcohols can be readily performed by this strategy.
Radical transfer hydrosilylation/cyclization using silylated cyclohexadienes
Amrein, Stephan,Timmermann, Andreas,Studer, Armido
, p. 2357 - 2360 (2007/10/03)
(matrix presented) A new method for mild metal-free hydrosilylation is described. Silylated cyclohexadienes are used as radical transfer hydrosilylating reagents for various double and triple bonds. A trialkylsilane is transferred from a cyclohexadiene mo