3561-84-0Relevant academic research and scientific papers
Iron oxide nanoparticles grown on carboxy-functionalized graphite: An efficient reusable catalyst for alkylation of arenes
Rajpara, Vikul,Banerjee, Subhash,Sereda, Grigoriy
experimental part, p. 2835 - 2840 (2010/10/04)
Here we report a simple procedure for the synthesis of a novel hybrid catalyst by growing iron oxide nanoparticles on carboxy-functionalized graphite. This hybrid catalyst demonstrated superior catalytic activity towards the alkylation of arenes with alkyl halides in contrast to commercial graphite or unsupported iron oxide nanoparticles in terms of yields and general applicability. The catalyst can be reused up to five times with a minimal loss of catalytic activity. Georg Thieme Verlag Stuttgart.
The synthetic potential of graphite-catalyzed alkylation
Sereda, Grigoriy A.,Rajpara, Vikul B.,Slaba, Ryan L.
, p. 8351 - 8357 (2008/02/07)
Unmodified graphite is introduced as a mild catalyst for alkylation of aromatic compounds and primary alcohols, applicable when utilization of strong Lewis acids is not feasible. The electrophilic intermediate has a significant carbocationic character and can be formed on a partially rate-limiting step.
Direct functionalization of arenes by primary alcohol sulfonate esters catalyzed by gold(III)
Shi, Zhangjie,He, Chuan
, p. 13596 - 13597 (2007/10/03)
Alkylation of arenes by primary alcohol triflate or methanesulfonate esters can be efficiently catalyzed by AuCl3 with silver triflate. Copyright
