35657-63-7

Upstream product

• 1569095-70-0 (2E)-N-methoxy-N-((1S)-1-phenylprop-2-en-1-yl)but-2-enamide 
• 50-00-0 formaldehyd 
• 295328-85-7 (2S,5S)‐diphenylpyrrolidine 
• 1569095-73-3 C₁₁H₁₁NO₂ 
• 1569095-79-9 (5S)-1-methoxy-5-phenylpyrrolidin-2-one 
• 109-99-9 tetrahydrofuran 
• 780-25-6 N-benzylidene benzylamine 
• 74-88-4 methyl iodide 
• 74-85-1 ethene 
• 1569096-23-6 (5S)-1-methoxy-5-phenylpyrrolidin-2-one-d3 
• 100-58-3 phenylmagnesium bromide 
• 87802-71-9 (E)-methyl cinnamyl carbonate 
• 1569096-41-8 tert-butyl methoxy[(1S)-1-phenylprop-2-en-1-yl]carbamate-d3 

Downstream Products

• 112176-00-8 (Z)-2,3-dibromo-1,4-diphenylbut-2-ene-1,4-dione 

Relevant academic research and scientific papers

Addition of organometallic reagents to chiral N-methoxylactams: Enantioselective syntheses of pyrrolidines and piperidines

Enantioselective iridium-catalyzed allylic substitutions were used to prepare N-allyl hydroxamic acid derivatives that were suitable for ring-closing metathesis, giving N-methoxylactams. Reactions of these derivatives with Grignard or organolithium compou

1,3-ANIONIC CYCLOADDITIONS OF 2-AZAALLYLLITHIUM COMPOUNDS TO ETHYLENE. SYNTHESIS OF 2,5-DIARYLPYRROLIDINES

Anionic cycloaddition of 1,3-diaryl-2-azaallyllithiums with the ethylene formed in situ by the cleavage of THF by n-butyllithium gave cis-2,5-diarylpyrrolidines in synthetically useful yields.The same cycloadducts were obtained from the reaction of 2a and 2c with ethylene itself.