357417-08-4

Upstream product

• 357417-36-8 cis-5-benzyloxy-4,6-bis(benzyloxymethyl)-2-phenyl-1,3-dioxane 
• 100-39-0 benzyl bromide 
• 358358-86-8 2,4-O-benzylidene xylitol 
• 7677-24-9 trimethylsilyl cyanide 

Downstream Products

• 357417-02-8 trans-2-diazoacetyl-cis-5-benzyloxy-4,6-bis(benzyloxymethyl)-2-methyl-1,3-dioxane 
• 357417-37-9 trans-2-carboxy-cis-5-benzyloxy-4,6-bis(benzyloxymethyl)-2-methyl-1,3-dioxane 
• 357417-10-8 trans-carboxymethyl-cis-5-benzyloxy-4,6-bis(benzyloxymethyl)-2-methyl-1,3-dioxane 
• 357417-09-5 trans-carboxyamide-cis-5-benzyloxy-4,6-bis(benzyloxymethyl)-2-methyl-1,3-dioxane 

Relevant academic research and scientific papers

Template-directed C-H insertion: synthesis of the dioxabicyclo[3.2.1]octane core of the zaragozic acids.

[reaction: see text] The preparation of (+/-)-24, a model for the core of the zaragozic acids, is reported. The pivotal reaction in this endeavor is the dirhodium(II)-catalyzed intramolecular C-H bond insertion of 2-diazoacetyl-1,3-dioxane 4, a transforma