357429-53-9Relevant academic research and scientific papers
1,3-diethynylallenes: New modules for three-dimensional acetylenic scaffolding
Livingston, Robert C.,Cox, Liam R.,Gramlich, Volker,Diederich, Francois
, p. 2334 - 2337 (2001)
Regioselective Pd0-catalized cross-coupling of bispropargylic precursors 1 with silyl-protected alkynes gave rise to the first 1,3-diethynylallenes 2 [Eq. (1), LG=leaving group]. In enantiometrically pure form, these novel carbon-rich modules c
1,3-Diethynylallenes: Carbon-rich modules for three-dimensional acetylenic scaffolding
Livingston, Robert,Cox, Liam R.,Odermatt, Severin,Diederich, Franois
, p. 3052 - 3077 (2007/10/03)
Regioselective Pd0-catalyzed cross-coupling of substrates, which bear bispropargylic leaving groups with silyl-protected alkynes, has provided access to a variety of 1,3-diethynylallenes, a new family of modules for three-dimensional acetylenic
