35755-80-7Relevant articles and documents
CONTROLLED ALKYLATION OF HYDROXYLAMINES WITH BUTADIENE CATALYZED BY PALLADIUM COMPLEXES
Fakhretdinov, R. N.,Telin, A. G.,Dzhemilev, U. M.
, p. 2059 - 2061 (1986)
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Synthetic method of allylamine
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Paragraph 0029; 0030, (2017/01/02)
The invention provides a synthetic method of allylamine compounds with substituted allyl alcohol and aromatic amines as raw materials through induction of a titanium metal intermediate. The invention relates to a secondary amine substituted by an allyl gr
Modular synthesis of 1,2-Diamine derivatives by palladium-Catalyzed aerobic oxidative cyclization of allylic sulfamides
McDonald, Richard I.,Stahl, Shannon S.
supporting information; experimental part, p. 5529 - 5532 (2010/09/05)
Chemical equation presented Allylic sulfamides undergo aerobic oxidative cyclization at room temperature, mediated by a Pd(O 2CCF3)2/DMSO catalyst system in tetrahydrofuran. The cyclic sulfamide products are readily converted into 1,2-diamines, and substrates derived from chiral allylic amines cyclize with very high diastereoselectivity.