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Ethanone, 1-(4-fluorophenyl)-2-[[(4-methylphenyl)sulfonyl]oxy]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 357952-79-5 Structure
  • Basic information

    1. Product Name: Ethanone, 1-(4-fluorophenyl)-2-[[(4-methylphenyl)sulfonyl]oxy]-
    2. Synonyms:
    3. CAS NO:357952-79-5
    4. Molecular Formula: C15H13FO4S
    5. Molecular Weight: 308.33
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 357952-79-5.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Ethanone, 1-(4-fluorophenyl)-2-[[(4-methylphenyl)sulfonyl]oxy]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Ethanone, 1-(4-fluorophenyl)-2-[[(4-methylphenyl)sulfonyl]oxy]-(357952-79-5)
    11. EPA Substance Registry System: Ethanone, 1-(4-fluorophenyl)-2-[[(4-methylphenyl)sulfonyl]oxy]-(357952-79-5)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 357952-79-5(Hazardous Substances Data)

357952-79-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 357952-79-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,5,7,9,5 and 2 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 357952-79:
(8*3)+(7*5)+(6*7)+(5*9)+(4*5)+(3*2)+(2*7)+(1*9)=195
195 % 10 = 5
So 357952-79-5 is a valid CAS Registry Number.

357952-79-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(4-Fluorophenyl)-2-(p-tolylsulfonyloxy)ethanone

1.2 Other means of identification

Product number -
Other names 2-(4-fluorophenyl)-2-oxoethyl 4-methylbenzenesulfonate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:357952-79-5 SDS

357952-79-5Relevant articles and documents

Diastereoselective Alkene Hydroesterification Enabling the Synthesis of Chiral Fused Bicyclic Lactones

Shi, Zhanglin,Shen, Chaoren,Dong, Kaiwu

supporting information, p. 18039 - 18042 (2021/11/16)

Palladium-catalysed diastereoselective hydroesterification of alkenes assisted by the coordinative hydroxyl group in the substrate afforded a variety of chiral γ-butyrolactones bearing two stereocenters. Employing the carbonylation-lactonization products as the key intermediates, the route from the alkenes with single chiral center to chiral THF-fused bicyclic γ-lactones containing three stereocenters was developed.

Regioselective three-component synthesis of 1,2-diarylindoles from cyclohexanones, α-hydroxyketones and anilines under transition-metal-free conditions

Li, Cheng,Xie, Yanjun,Xiao, Fuhong,Huang, Huawen,Deng, Guo-Jun

supporting information, p. 4079 - 4082 (2019/04/25)

A facile method for the one-pot synthesis of 1,2-diarylindoles under transition-metal-free conditions is described. Cyclohexanones were used as the aryl sources via the dehydrogenative aromatization process. One C-C and two C-N bonds were selectively formed via a domino reaction. This protocol provides a convenient approach for the construction of valuable bioactive 1,2-diarylindoles from readily available cyclohexanones, α-hydroxyketones and anilines.

Facile synthesis of polysubstituted cyclopropanes using α-tosyloxyketones

Rana, Neena,Nain, Sonia,Kumar, Dinesh,Kumar, Ravi

, p. 505 - 507 (2018/02/09)

A facile synthesis of polysubstituted cyclopropanes (5) by the treatment of pyridinium ylides, generated in situ from pyridinium toslyates (2), with arylidenemalonitrile (4) is presented. Pyridinium toslyates (2) were obtained by reacting α-tosyloxyketone

Metal-free C(sp3)-H bond sulfonyloxylation of 2-alkylpyridines and alkylnitrones

Wang, Chang-Sheng,Dixneuf, Pierre H.,Soulé, Jean-Fran?ois

, p. 4954 - 4957 (2018/07/25)

Pyridin-2-ylmethyl tosylate derivatives are obtained in high yields from 2-alkylpyridine 1-oxides via a [3,3]-sigmatropic rearrangement of the adduct between 2-alkylpridine 1-oxides with benzenesulfonyl chlorides. Moreover, alkylnitrones also undergo [3,3]-sigmatropic rearrangement to give α-tosylated ketones after hydrolysis. Substitution reactions with nucleophiles then lead to diverse useful functionalizations for the synthesis of pincer ligands.

A convenient [hydroxy(tosyloxy)iodo]benzene-mediated one-pot synthesis of 2-arylimidazo[2,1-b[benzothiazoles

Sumran, Garima,Aggarwal, Ranjana

, p. 170 - 177 (2015/10/20)

Several 2-arylimidazo[2,1-b]benzothiazoles (4) have been conveniently synthesized in one-pot reactions via α-tosyloxylation of enolizable ketones (1) using [hydroxy(tosyloxy)iodo]benzene 2 in acetonitrile, followed by treatment with 2-amino-6-(substituted

Modified one-pot multicomponent diastereoselective synthesis of trans-2,3-Dihydrofuro[3,2-c]coumarins via in situ-generated α- tosyloxyketones

Kumar, Ravi,Wadhwa, Deepak,Hussain, Khalid,Prakash, Om

, p. 1802 - 1807 (2013/05/22)

A modified protocol for diastereoselective synthesis of differently substituted trans-2,3-dihydrofuro[3,2-c]coumarins is developed via, a one-pot multicomoponent reaction starting from aromatic aldehydes, 4-hydroxycoumarin, and α-tosyloxyacetophenones wit

An iodobenzene-catalysed domino route toward quinoxaline derivatives from simple ketones and o-phenylenediamines in one pot

Li, Xiaoqing,Zhou, Can,Hu, Zhiyan,Xu, Xiangsheng

, p. 579 - 581 (2013/10/22)

An iodobenzene-catalysed domino route to quinoxalines from ketones and o-phenylenediamines in one pot has been developed. This transformation consisted of the generation of Koser's generation, α-tosyloxylation of ketones, nucleophilic substitution and intramolecular dehydration with o-phenylenediamines, and dehydrogenation. Website

Catalytic, asymmetric, interrupted Feist-Benary reactions of α-tosyloxyacetophenones

Calter, Michael A.,Korotkov, Alexander

supporting information; experimental part, p. 6328 - 6330 (2012/01/11)

A new variant of the Interrupted Feist-Benary (IFB) reaction uses α-tosyloxyacetophenones as electrophiles and proceeds in good yields and excellent enantioselectivities.

Iodobenzene-catalyzed synthesis of α-azidoketones and α-thiocyanatoketones from aryl ketones with MCPBA as a cooxidant

Chang, Ya-Li,Chung, Chi-Lin,Wu, Fang-Wen,Wang, Huey-Min,Hou, Rei-Sheu,Kang, Iou-Jiun,Chen, Ling-Ching

experimental part, p. 149 - 152 (2011/04/16)

Iodobenzene-catalyzed synthesis of α-azidoketones and α-thiocyanatoketones from aryl ketones with MCPBA as a cooxidant is described. The method is simple, rapid and practical, generating α-azidoketones and α-thiocyanatoketones from the aryl ketone without

Iodobenzene-catalyzed synthesis of imidazo[1,2-a]pyridines from aryl ketones with mCPBA in ionic liquid

Chang, Ya-Li,Wang, Huey-Min,Hou, Rei-Sheu,Kang, Iou-Jiun,Chen, Ling-Ching

experimental part, p. 153 - 156 (2011/04/16)

Iodobenzene-catalyzed synthesis of imidazo[1,2-a]pyridines from aryl ketones with mCPBA as a cooxidant in ionic liquid is described. The method is simple, rapid and practical, generating Imidazo[1,2-a]pyridines from the aryl ketone without isolation of α-

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