358723-67-8Relevant articles and documents
The preparation of 3- (2-phenylethenyl)-1H-pyrazoles from dilithiated (3E)-4-phenyl-3-buten-2-one hydrazones
Pastine,Kelley W.,Bear,Templeton III,Beam
, p. 539 - 548 (2001)
The phenyl-, carbomethoxy-, and carboethoxy-hydrazones of (3E)-4-phenyl-3-buten-2-one [benzalacetone] were treated with excess lithium diisopropylamide, and the resulting 1,4-dianions were condensed with several aromatic esters, followed by acid cyclizati
Cu(ii)-Catalyzed asymmetric boron conjugate addition to α,β-unsaturated imines in water
Kitanosono, Taku,Xu, Pengyu,Isshiki, Satoshi,Zhu, Lei,Kobayashi, Shu
supporting information, p. 9336 - 9339 (2014/08/05)
Enantioselective conjugate addition of bis(pinacolato)diboron to α,β-unsaturated imines proceeds smoothly in water in the presence of a chiral copper(ii) complex consisting of Cu(OAc)2 and chiral 2,2′-bipyridine. The corresponding β-boryl imines, which were oxidized to β-hydroxy imines, further leading to γ-amino alcohols, were obtained in high yields and high enantioselectivities.