35919-95-0

Upstream product

• 39680-11-0 C₃₁H₃₂O₇S₂ 
• 75-08-1 ethanethiol 
• 39680-15-4 4,5,6-tri-O-acetyl-2,3-di-S-ethyl-2,3-dithio-D-allose diethyl dithioacetal 
• 98-88-4 benzoyl chloride 
• 29364-56-5 3,5,6-tri-O-acetyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 6339-03-3 O³,O⁵,O⁶-tribenzoyl-O¹,O²-isopropylidene-α-D-glucofuranose 

Downstream Products

• 35810-80-1 C₃₃H₃₈O₈S₂ 
• 35810-74-3 C₂₉H₂₆O₇S 

Relevant academic research and scientific papers

An improved synthesis of D-amicetose

This paper reports on the acid-catalyzed ethanethiolysis of 3,5-di-O-acetyl-6-S-acetyl-1,2-O-isopropylidene-6-thio- α-D-glucofuranose and 3,5,6-tri-O-benzoyl-1,2-O-isopropylidene-α-D-glucofuranose.

THE ACTION OF THIOLS ON DERIVATIVES OF D-XYLOSE

The action of thiols on 1,2,3,4-tetra-O-acetyl β-D-xylopyranose gave 2- and 5-alkylthiopentose dithioacetals and alkyl 1-thio-D-xylopyranosides.On treatment with thiols and trifluoroacetic acid, 3-O-acetyl-1,2-O-isopropylidene-α-D-xylofuranose derivatives rapidly formed 4-O-acetyl-2,3-dialkylthio-D-ribose dithioacetal derivatives, which were in turn converted into 4-O-acetyl-3-S-benzyl-2,5-epithio-3-thio-D-ribose (or D-arabinose) dithioacetal.