3594-88-5

Basic information

• Product Name: [1,1'-Biphenyl]-2-ol, 2'-methoxy-
• CAS NO: 3594-88-5
• Molecular Formula: C13H12O2
• Molecular Weight: 200.237
• Mol File: 3594-88-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: [1,1'-Biphenyl]-2-ol, 2'-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-Biphenyl]-2-ol, 2'-methoxy-(3594-88-5)
• EPA Substance Registry System: [1,1'-Biphenyl]-2-ol, 2'-methoxy-(3594-88-5)

Safety Data

• Hazardous Substances Data: 3594-88-5(Hazardous Substances Data)

Usage

General Description

[1,1'-Biphenyl]-2-ol, 2'-methoxy- is a chemical compound that belongs to the class of biphenyl derivatives. It has a molecular formula C13H12O2 and a molecular weight of 200.24 g/mol. [1,1'-Biphenyl]-2-ol, 2'-methoxy- is commonly used in research and pharmaceutical applications due to its unique properties. It has been studied for its potential biological activities, including its anti-inflammatory and antioxidant properties. Additionally, [1,1'-Biphenyl]-2-ol, 2'-methoxy- has also been investigated for its potential use in the synthesis of organic compounds and its role in the development of new materials. Overall, this chemical compound has a wide range of potential applications in various fields and continues to be the subject of scientific interest and investigation.

Upstream product

• 65109-75-3 N-(phenoxy)-4-methylbenzenesulfonamide 
• 100-66-3 methoxybenzene 
• 95-56-7 2-hydroxybromobenzene 
• 5720-06-9 2-Methoxyphenylboronic acid 

Downstream Products

• 141778-86-1 3-bromo-2'-methoxybiphenyl-2-ol 
• 86-26-0 2-methoxy-1,1'-biphenyl 
• 32750-04-2 3.5.3'.5'-Tetranitro-2.2'-dihydroxy-biphenyl 
• 128957-57-3 C₅₁H₅₄N₄O₉ 
• 156660-03-6 C₅₂H₅₅N₃O₉ 
• 156659-99-3 C₄₅H₄₂N₄O₉ 
• 156660-02-5 C₃₇H₄₃N₃O₆ 
• 156660-01-4 3-(2,2'-dimethoxybiphenyl)-3-carbonyl-1,3-thiazolidine-2-thione 
• 141778-89-4 3-bromo-2',2'-dimethoxybiphenyl 

Relevant articles and documents

An aromatic heterocyclic compound and use thereof

The invention provides an aromatic heterocyclic compound. The compound is as shown in formula (1), wherein Y1 is an oxygen atom or a sulfur atom; Y2 is an oxygen atom, a sulfur atom, NR3 or CR1R2, wherein R1, R2 are respectively selected from one of a hydrogen atom, a methyl group, an ethyl group, a propyl group, a tert-butyl group and a phenyl group, and R3 is the hydrogen atom or the phenyl group; X11-X20 are respectively selected from a nitrogen atom or CR4, and at least one of the X11-X20 is a carbon atom which is linked to L1 through a single bond, wherein R4 is the hydrogen atom, a halogen atom or a cyano group; at least one of the X17-X20 is the nitrogen atom. According to the aromatic heterocyclic compound, the aromatic heterocyclic compound has a similar structure as a dibenzofuran derivative and a dibenzothiophene derivative, electron transport can be improved, high light, low voltage, high efficiency and long service life of an organic EL component can be achieved, and the aromatic heterocyclic compound can be extensively applied in an OLED luminescent device and a display device to be used as the host material of a luminescent layer.

A mild robust generic protocol for the Suzuki reaction using an air stable catalyst

A mild but robust procedure has been developed as a first pass generic protocol for the Suzuki-Miyaura reaction. The protocol employs an air stable palladium pre-catalyst at low loading (1 mol %) in aqueous solvent mixtures at moderate temperature using potassium carbonate as base. Under these mild conditions, most aryl bromides will react with sterically and electronically demanding aryl boronic acids to give complete conversion to the product biphenyls in less than 1 h. Aryl chlorides are also fully converted in most cases either under identical conditions in 8-24 h, or in 2 h at elevated temperature. A further advantage of these mild conditions of moderate temperature, weak base and benign solvent is that sensitive functional groups and structural motifs are well tolerated. In addition, the lipophilic biphenyl products are readily isolated after a simple work-up procedure. These generic conditions are ideal for proof of transformation, and as the starting point for development and optimization of a specific process. The discovery and fine-tuning of this generic protocol will be presented, supported extensively by examples to illustrate its scope and utility.

Acid-Catalyzed Solvolysis of N-Sulfonyl- and N-Acyl-O-arylhydroxylamines. Phenoxenium Ions

The acid-catalyzed reaction of N-acyl- and N-sulfonyl-O-arylhydroxylamines with benzene proceeded quite smoothly to give 2- and 4-hydroxybiphenyls.The results of product analysis, the orientation of the reaction, and the effects of substituents on the nitrogen atom and on the phenyl ring suggested a mechanism that involves a phenoxenium ion.The phenoxenium ion was trapped by benzene and other various nucleophiles.