65109-75-3

Basic information

• Product Name: Benzenesulfonamide, 4-methyl-N-phenoxy-
• CAS NO: 65109-75-3
• Molecular Formula: C13H13NO3S
• Molecular Weight: 263.317
• Mol File: 65109-75-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, 4-methyl-N-phenoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, 4-methyl-N-phenoxy-(65109-75-3)
• EPA Substance Registry System: Benzenesulfonamide, 4-methyl-N-phenoxy-(65109-75-3)

Safety Data

• Hazardous Substances Data: 65109-75-3(Hazardous Substances Data)

Upstream product

• 4846-21-3 O-phenylhydroxylamine 
• 98-59-9 p-toluenesulfonyl chloride 
• 6092-80-4 phenoxyamine hydrochloride 
• 98-80-6 phenylboronic acid 
• 64908-64-1 2-phenoxyisoindol-1,3-dione 

Downstream Products

• 65109-81-1 2-hydroxyphenyl p-toluenesulfonimidate 
• 129560-99-2 4-(2,2,2-trifluoroethoxy)phenol 
• 65109-80-0 4-hydroxyphenyl trifluoromethanesulfonate 
• 160968-99-0 2-O-(2,2,2-trifluoroethyl)catechol 
• 2848-25-1 2-acetoxyphenol 
• 3233-32-7 hydroquinone monoacetate 
• 21849-91-2 2-(4-methoxyphenyl)phenol 
• 3594-88-5 2-(2-methoxyphenyl)phenol 
• 16881-71-3 4'-methoxy-1,1'-biphenyl-4-ol 
• 65109-82-2 2'-methoxy-1,1'-biphenyl-4-ol 
• 103-90-2 4-acetaminophenol 
• 127291-60-5 4,N-Dimethyl-N-phenoxy-benzenesulfonamide 
• 92-69-3 4-Phenylphenol 
• 70-55-3 toluene-4-sulfonamide 

Relevant articles and documents

Hexafluoroisopropanol (HFIP)-prompted rearrangement of N-phenoxysulfonamides for the direct assembly of ortho-sulfonamide phenols: A combined experimental and computational study

ortho-Sulfonamide phenols represent a class of attractive structural motifs in medicinal and synthetic chemistry. Herein an efficient metal-free rearrangement reaction has been developed for the construction of ortho-sulfonamide phenols via HFIP-prompted

Rhodium(III)-catalyzed redox-neutral coupling of N-phenoxyacetamides and alkynes with tunable selectivity

Give it a tweak: A novel oxidizing directing group was developed for a rhodium(III)-catalyzed C-H functionalization of N-phenoxyacetamides with alkynes. A small change in the reaction conditions leads to either ortho-hydroxyphenyl-substituted enamides or cyclization to deliver benzofurans with high selectivity (see scheme; Cp=C5Me5). Copyright

O-Substituted N-oxy arylsulfinamides and sulfonamides in Michael reactions

O-Substituted N-oxy arylsulfinamides and sulfonamides undergo fast aza-Michael reaction in the presence of base and electron-deficient α,β-unsaturated olefins under mild conditions. With N-silyloxy benzenesulfinamides, no aza-Michael product is observed and a hetero aza-Brook type rearrangement takes place induced by the base. Room temperature N-desulfinylation of N-benzyloxybenzenesulfinamide is achieved using BF 3.Et2O. N-Alkoxy arylsulfonamides aza-Michael adducts are found to be generally highly stable under strongly acidic and basic conditions.