359882-23-8

Basic information

• Product Name: 1,2-Pyrrolidinedicarboxylic acid, 2-[(2-bromo-4-methoxyphenyl)methyl]-4-hydroxy-, 2-methyl 1-(phenylmethyl) ester, (2R,4R)-
• CAS NO: 359882-23-8
• Molecular Formula: C22H24BrNO6
• Molecular Weight: 478.34
• Mol File: 359882-23-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,2-Pyrrolidinedicarboxylic acid, 2-[(2-bromo-4-methoxyphenyl)methyl]-4-hydroxy-, 2-methyl 1-(phenylmethyl) ester, (2R,4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Pyrrolidinedicarboxylic acid, 2-[(2-bromo-4-methoxyphenyl)methyl]-4-hydroxy-, 2-methyl 1-(phenylmethyl) ester, (2R,4R)-(359882-23-8)
• EPA Substance Registry System: 1,2-Pyrrolidinedicarboxylic acid, 2-[(2-bromo-4-methoxyphenyl)methyl]-4-hydroxy-, 2-methyl 1-(phenylmethyl) ester, (2R,4R)-(359882-23-8)

Safety Data

• Hazardous Substances Data: 359882-23-8(Hazardous Substances Data)

Downstream Products

• 359882-24-9 (R)-1-benzyloxycarbonyl-2-(2-bromo-4-methoxyphenyl)methyl-2-methoxycarbonyl-4-oxopyrrolidine 
• 359882-26-1 (1S,4R)-3-benzyloxycarbonyl-8-methoxy-4-methoxycarbonyl-1-phenylthiomethyl-2,3,4,5-tetrahydro-1,4-methano-3-benzazepine 
• 359882-20-5 (1S,9R)-4-Methoxy-1-phenylsulfanylmethyl-10-aza-tricyclo[7.2.1.0^2,7]dodeca-2⁽⁷⁾,3,5-triene-9,10-dicarboxylic acid 10-benzyl ester 
• 359882-25-0 (S)-1-benzyloxycarbonyl-2-[(2-bromo-4-methoxyphenyl)methyl]-2-methoxycarbonyl-4-(phenylthiomethylene)pyrrolidine 
• 359882-21-6 (1S,4R)-3-benzyloxycarbonyl-8-methoxy-1-phenylthiomethyl-2,3,4,5-tetrahydro-1,4-methano-3-benzazepine 
• 128524-63-0 (+)-8-O-methylaphanorphine 
• 118964-06-0 (-)-aphanorphine 

Relevant articles and documents

Synthesis of (-)-aphanorphine using aryl radical cyclization.

[structure: see text] The synthesis of (-)-aphanorphine was achieved by using Bu(3)SnH-mediated aryl radical cyclization of 1-benzyloxycarbonyl-2-(2-bromo-4-methoxyphenylmethyl)-2-methoxycarbonyl-4-(phenylthiomethylene)pyrrolidine, leading to exclusive fo