3609-45-8

Basic information

• Product Name: Benzene, 1-chloro-2-(1-methylethenyl)-
• CAS NO: 3609-45-8
• Molecular Formula: C9H9Cl
• Molecular Weight: 152.623
• Mol File: 3609-45-8.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-2-(1-methylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-2-(1-methylethenyl)-(3609-45-8)
• EPA Substance Registry System: Benzene, 1-chloro-2-(1-methylethenyl)-(3609-45-8)

Safety Data

• Hazardous Substances Data: 3609-45-8(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 610-96-8 methyl chlorobenzoate 
• 3670-15-3 2-(2-chlorophenyl)propan-2-ol 
• 75-24-1 trimethylaluminum 
• 88-16-4 1-chloro-2-(trifluoromethyl)benzene 
• 2142-68-9 1-(2-chlorophenyl)ethanone 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 1239700-56-1 2-(1-(2-chlorophenyl)vinyl)-4,4,5,5-tetramethyl-1,3-dioxa-2-borolane 
• 74-88-4 methyl iodide 
• 7335-25-3 ethyl 2-chlorobenzoate 
• 1206451-01-5 2-(2-bromo-6-chlorophenyl)-2-methylpropanal 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 108-24-7 acetic anhydride 
• 2065-66-9 methyl-triphenylphosphonium iodide 

Downstream Products

• 23417-79-0 2-(1-methylethenyl)benzaldehyde 
• 6416-39-3 1-methyl-3-phenylindan 
• 55006-57-0 1,3-dimethyl-3-(o-chlorophenyl)-indan 
• 1064000-91-4 C₁₀H₉Br₂Cl 
• 21190-34-1 (2-isopropylphenyl)methanol 
• 15582-48-6 o-1-menthene 
• 15582-49-7 o-2-menthene 
• 180092-32-4 [2-(1-methylethenyl)phenyl]methyl alcohol 
• 1064001-47-3 1-chloro-2-(1-methylcycloprop-2-en-1-yl)benzene 

Relevant articles and documents

Visible-light-promoted radical alkylation/cyclization of allylic amide with N-hydroxyphthalimide ester: Synthesis of oxazolines

An efficient photocatalytic alkylation/cyclization of allylic amide with N-hydroxyphthalimide ester has been developed. The transformation is taken advantage of alkyl radicals to attack allylic amide with the assist of inexpensive rose bengal as photocatalyst to prepare a series of alkyl substituted oxazolines in moderate to excellent yields. High regioselectivity, operational safety, mild conditions and excellent substrate generality give this protocol broad application prospects.

Stereoselective Synthesis of Vinylcyclopropa[ b]indolines via a Rh-Migration Strategy

A mild rhodium catalytic system has been developed to synthesize vinylcyclopropa[b]indolines through cyclopropanation of indoles with vinyl carbenoids generated from ring opening of cyclopropenes in situ. By employing a Rh-migration strategy, the products can be obtained with good to excellent E:Z ratios (≤99:1) and complete diastereoselectivity (≤99:1). This method is easy, has a low catalyst loading, and works for a broad range of functionalities.

Synthesis of N-Alkylpyridin-4-ones and Thiazolo[3,2- a]pyridin-5-ones through Pummerer-Type Reactions

N-Alkylated 4-pyridones were obtained through a one-pot procedure involving either normal or interrupted Pummerer reactions between triflic anhydride-activated sulfoxides and 4-fluoropyridine derivatives, followed by hydrolysis. On the other hand, triflic anhydride-activated benzyl 6-fluoro-2-pyridyl sulfoxide could react with alkenes or alkynes to afford thiazolo[3,2-a]pyridin-5-ones, via the pyridinium salt intermediates.